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咪唑啉类缓蚀剂在模拟沉积物层中的扩散行为研究

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采用紫外-可见分光光度法(UV-Vis)和动电位极化曲线法研究了三种咪唑啉类缓蚀剂(SOIMS,SOIM和OIM)在模拟沉积物层中的扩散行为.通过SEM(扫描电镜)和压汞法试验对试验前后的模拟沉积物层进行了表征.UV-Vis法试验结果表明:缓蚀剂在溶液中的扩散行为与其水溶性密切相关,缓蚀剂的水溶性越好,其通过沉积物层的能力越强.UV-Vis法试验和动电位极化曲线试验结果表明:随着试验时间的增加,三种缓蚀剂均能通过模拟沉积物层.
Study on the diffusion behavior of imidazoline corrosion inhibitor in simulated sediment layer
The diffusion behaviors of three imidazoline corrosion inhibitors(SOIMS,SOIM,and OIM)in simulated sediment layer were studied by adopting UV-Vis and potential dynamic polarization curve.The simulated sediment layer before and after the experiment were characterized by SEM(scanning electron microscopy)and mercury intrusion porosimetry.UV-Vis test re-sults showed that the diffusion behavior of corrosion inhibitors in solution is closely related to the water solubility;the better the water solubility of corrosion inhibitors,the stronger their ability to pass through sediment layer.The results of UV-Vis test and potential dynamic polarization curve test proved that all three corrosion inhibitors can pass through simulated sediment layer as test time increases.

corrosion inhibitordiffusionsediment layerUV-Vispotential dynamic polarization curve

赵景茂、铁志伟、张存丽

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北京化工大学材料科学与工程学院,北京 100029

胜利油田临盘采油厂,山东德州 251507

缓蚀剂 扩散 沉积物层 紫外-可见分光光度 动电位极化曲线

胜利油田2022-2023年重点实验室项目

YKS2204

2024

石油化工腐蚀与防护
中国石化集团洛阳石化工程公司

石油化工腐蚀与防护

影响因子:0.327
ISSN:1007-015X
年,卷(期):2024.41(4)