石油化工应用2024,Vol.43Issue(2) :90-97.DOI:10.3969/j.issn.1673-5285.2024.02.019

非均相Fenton降解甲基橙染料废水流化床实验

Heterogeneous Fenton degradation of methyl orange dye wastewater fluidized bed experiments

郭蓉蓉 刘欣 陈爽 白建军 张林琳
石油化工应用2024,Vol.43Issue(2) :90-97.DOI:10.3969/j.issn.1673-5285.2024.02.019

非均相Fenton降解甲基橙染料废水流化床实验

Heterogeneous Fenton degradation of methyl orange dye wastewater fluidized bed experiments

郭蓉蓉 1刘欣 2陈爽 1白建军 1张林琳1
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作者信息

  • 1. 中国石油大学(华东)化学化工学院,重质油国家重点实验室,山东青岛 266580
  • 2. 中国石化胜利石油管理局有限公司供水分公司,山东东营 257045
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摘要

在(25±5)℃下,将β-FeOOH负载在SiO2上得到β-FeOOH/SiO2,作为非均相Fenton催化剂,在流化床装置中探究对甲基橙染料废水的降解效果及降解机制,结合XRD、FT-IR表征手段探究β-FeOOH/SiO2在流化床工艺中的适用性、循环利用性以及稳定性.结果表明,β-FeOOH/SiO2添加量为5.00 g/L,H2O2添加量为0.031 L/L,反应83 min,对250 mg/L甲基橙染料废水的去除率可达100%,COD去除率为88.36%,TOC去除率为67.5%.β-FeOOH/SiO2 与流化床结合具有适用性较广、去除率高等优点.

Abstract

At(25±5)℃,the β-FeOOH was loaded on SiO2 to praper β-FeOOH/SiO2,which was used as heterogeneous Fenton catalyst.The degradation effect and degradation mechanism of methyl orange dye wastewater were investigated in fluidized bed device.The applicability,recycling and stability of β-FeOOH/SiO2 in fluidized bed process were investi-gated by XRD and FT-IR characterization methods.The results showed that the addition of β-FeOOH/SiO2 was 5.00 g/L,H2O2 was 0.031 L/L,the reaction time was 83 min and the re-moval rate of 250 mg/L methyl orange dye wastewater was 100%,COD was 88.36%,and TOC was 67.5%.The β-FeOOH/SiO2 combined with fluidized bed has the advantages of wide applicability and high removal rate.

关键词

β-FeOOH/SiO2/流化床/甲基橙/Fenton

Key words

β-FeOOH/SiO2/fluidized bed/methyl orange/Fenton

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基金项目

国家自然科学基金(22078366)

出版年

2024
石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
参考文献量40
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