首页|浅层稠油化学降黏技术研究及应用

浅层稠油化学降黏技术研究及应用

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针对浅层稠油油藏埋深浅、原油黏度高、热采动用效果差等开发难题,从稠油致黏机理、降黏机理、降黏剂靶向合成和性能评价等方面开展稠油化学降黏技术研究.通过分子动力学方法阐明了稠油中沥青质分子间π-π作用主导的致黏机理,其中,沥青质的面面堆积占主导作用.设计甲基丁香酚-丙烯酰胺-丙烯酸十八酯三元共聚物降黏剂分子结构,分子动力学结果显示,降黏剂可有效降低沥青质分子间π-π作用,降低稠油黏度.以甲基丁香酚、丙烯酰胺和丙烯酸十八酯为原料,优化合成降黏剂,该降黏剂在1 000 mg/kg浓度下可实现净降黏率 29.3%.在春风稠油油藏排 601-20区块开展矿场试验,日产油量增加 11.0 t,含水率下降 6.0%,产出投入比为 1.43∶1.试验效果验证了稠油降黏剂的可行性及有效性,可以为稠油化学降黏技术的发展提供理论指导.
Research and application of chemical viscosity reduction technology for shallow heavy oil
In order to deal with shallow formation depth,high oil viscosity and low thermal efficiency for shallow heavy oil reservoirs,the viscous mechanism,viscosity-reduction mech-anism,viscosity reducer synthesis and performance evaluation are investigated.The molecu-lar dynamics are used to indicate the heavy oil viscous mechanism by π-π stacking of as-phaltene,in which,the surface stacking is dominant.The molecular structure of methyleugenol-acrylsmide-octadecyl acrylate is designed,and molecular dynamics shows that this viscosity reducer can effectively reduce π-π stacking of asphaltene and reduce the heavy oil viscosity.The viscosity reducer is synthesized from methyleugenol,acrylsmide,and octadecyl acrylate.The net viscosity reduction rate can reach 29.3%at the mass fraction of 1 000 mg/kg.The pilot test is conducted in Pai 601-20 block of Chunfeng oilfield.The daily oil production rate is raised by 11.0 t,the water cut is reduced by 6.0%and output-input ratio is 1.43∶1 after the viscosity reducer is applied.The pilot test proved the effectiveness and feasibility of the chemical viscosity reducer,which can provide theoretical guidance for chemical viscosity reduction technique.

molecular dynamicsviscous mechanismterpolymerviscosity reductionfield application

刘京煊、关松涛、李斌、杨元亮、包正强

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中国石化新疆新春石油开发有限责任公司,山东东营 257000

分子动力学 致黏机理 三元共聚物 降黏 矿场应用

中国石化科技攻关计划

P23103

2024

石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
年,卷(期):2024.43(3)
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