3-氨基吡唑-4-羧酸Ni(Ⅱ)基配合物对高氯酸铵催化作用的研究
The catalytic effect of a Ni(Ⅱ)complex towards ammonium perchlorate based on 3-aminopyrazole-4-carboxylic acid
马娟 1杨燕红 1梁家维 1麻晓霞1
作者信息
- 1. 宁夏大学化学化工学院,宁夏银川 750021
- 折叠
摘要
以含能配体 3-氨基吡唑-4-羧酸(H2apza)构筑了一种新型Ni(Ⅱ)基配合物Ni(Hapza)2(H2O)4,利用元素分析、红外光谱、紫外光谱、热重分析等对其进行结构表征.利用差示扫描量热测试和Kissinger方法研究了配合物对高氯酸铵(AP)的催化性能,结果表明,该配合物对AP具有良好的催化作用.
Abstract
A novel Ni(Ⅱ)based complex Ni(Hapza)2(H2O)4 was constructed by an ener-getic ligand 3-aminopyrazole-4-carboxylic acid(H2apza).Elemental analysis,infrared spec-troscopy,ultraviolet spectroscopy and thermogravimetric analysis were used to determine the structure of the complex.The catalytic performance of the complex towards ammonium per-chlorate(AP)was studied using differential scanning calorimetry and Kissinger method,which indicate that the complex has a good catalytic effect on AP.
关键词
配合物/3-氨基吡唑-4-羧酸/高氯酸铵Key words
complex/3-aminopyrazole-4-carboxylic acid/ammonium perchlorate引用本文复制引用
基金项目
宁夏大学研究生创新项目(CXXM202416)
出版年
2024
NETL
NSTL
万方数据