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乳化性能对乳液聚合体系稳定性及反应过程的影响

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反相乳液聚合是合成聚丙烯酰胺一种重要的聚合方式,乳液体系由聚合单体水溶液、溶剂及乳化剂组成,体系的乳化性能对乳液的稳定性、聚合反应过程及产品粒径分布具有重要影响.本文通过研究体系中亲水乳化剂含量、总乳化剂含量、亲油/亲水乳化剂配比对乳液稳定性及聚合过程的影响,精确计算每组实验乳液体系的乳化性能,确定了水油比例为 1.5 时,粒径200~450 nm产品乳化体系稳定、反应过程较好的乳化性能区间,为后续同类反应研究提供参考.
Effect of emulsifying properties on the stability and reaction process of emulsion polymerization system
Reversed-phase emulsion polymerization is an important polymerization method for the synthesis of polyacrylamide,the emulsion system is composed of an aqueous solution of polymeric monomer,a solvent and an emulsifier,the emulsifying performance of the sys-tem has an important impact on the stability of the emulsion,the polymerization reaction process and the particle size distribution of the product.In this paper,the effects of hy-drophilic emulsifier content,total emulsifier content,and lipophilic/hydrophilic emulsifier ra-tio on the stability and polymerization process of the emulsion were studied,and the emulsi-fication performance of each group of experimental emulsion systems was accurately calcu-lated.The experimental conclusion shows that when the water-oil ratio is 1.5,the emulsifi-cation system of the product with a particle size of 200~450 nm is stable and the reaction process is better,it provides a reference for follow-up research on similar reactions.

emulsifying propertiesacrylamideemulsion polymerizationemulsion stability

赵笑男、孙烨、王鑫

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西安万德能源化学股份有限公司,陕西西安 710100

乳化性能 丙烯酰胺 乳液聚合 乳液稳定性

2024

石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
年,卷(期):2024.43(9)