石油化工应用2024,Vol.43Issue(11) :109-113.DOI:10.3969/j.issn.1673-5285.2024.11.024

g-C3N4/Ag3PO4复合Z型光催化剂的制备及对磺胺噻唑的光催化降解

Preparation of g-C3N4/Ag3PO4 composite Z-type photocatalyst and photocatalytic degradation of sulfathiazole

杨嘉伟 王阳阳 孙磊 樊超生 杨柳
石油化工应用2024,Vol.43Issue(11) :109-113.DOI:10.3969/j.issn.1673-5285.2024.11.024

g-C3N4/Ag3PO4复合Z型光催化剂的制备及对磺胺噻唑的光催化降解

Preparation of g-C3N4/Ag3PO4 composite Z-type photocatalyst and photocatalytic degradation of sulfathiazole

杨嘉伟 1王阳阳 1孙磊 1樊超生 1杨柳1
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作者信息

  • 1. 兰州交通大学环境与市政工程学院,甘肃 兰州 730030
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摘要

该研究采用简单的原位沉积法制备了g-C3N4/Ag3PO4 复合Z-异质结光催化剂,并将其用于磺胺噻唑(STZ)的降解.当g-C3N4 与Ag3PO4 的理论质量比为 1∶5(记为AG-5)时,STZ的降解效果最好,10 min内降解率可达 95.6%.此外,活性物种的捕获表明,光生空穴(h+)在反应中起主要作用.最后,用紫外-可见漫反射光谱对催化剂的光学性质和能带结构进行了分析,提出了Z型异质结电荷转移机理.

Abstract

In this study,a g-C3N4/Ag3PO4 composite Z-heterojunction photocatalyst was prepared with a simple in situ deposition method,and was applied to the degradation of sul-fathiazole(STZ).When the theoretical g-C3N4 to Ag3PO4 mass ratio was 1∶5(denoted as AG-5),the STZ degradation was optimal,and the degradation efficiency reached 95.6%within 10 min.In addition,capture of the active species showed that photogenerated holes(h+)played a major role in the reaction.Finally,the optical properties and the energy band structure of the catalyst were analyzed by UV-VIS diffuse reflectance spectroscopy(DRS),and a Z-type heterojunction charge transfer mechanism was proposed.

关键词

g-C3N4/Ag3PO4/Z型异质结/光催化降解/机理研究/磺胺噻唑

Key words

g-C3N4/Ag3PO4/Z-type heterojunction/photocatalytic degradation/mechanism research/sulfathiazole

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出版年

2024
石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
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