石油化工应用2024,Vol.43Issue(12) :99-102,116.DOI:10.3969/j.issn.1673-5285.2024.12.021

喹啉磷酸酯复配类缓蚀剂制备及性能研究

Preparation and properties of quinoline phosphate compound corrosion inhibitors

臧硕 张勇 赵璐 贾永富 芦义鹏 刘学敏
石油化工应用2024,Vol.43Issue(12) :99-102,116.DOI:10.3969/j.issn.1673-5285.2024.12.021

喹啉磷酸酯复配类缓蚀剂制备及性能研究

Preparation and properties of quinoline phosphate compound corrosion inhibitors

臧硕 1张勇 1赵璐 1贾永富 1芦义鹏 1刘学敏1
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作者信息

  • 1. 中海油(天津)油田化工有限公司,天津 300452
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摘要

为了验证磷酸酯类缓蚀剂在高温有氧工况下的缓蚀性能,采用聚乙二醇(PEG400)、苯酚、正辛醇、P2O5 为原料,合成一种聚乙二醇类磷酸酯,将聚乙二醇类磷酸酯与喹啉氯化苄类季铵盐等复配后形成一种喹啉磷酸酯复配类缓蚀剂.通过电化学评价研究了喹啉磷酸酯复配类缓蚀剂的缓蚀效果,通过高温高压釜评价研究了缓蚀剂在高温有氧工况下的防护效果.结果表明:在 180℃、2 MPa CO2+0.02 MPa O2 工况下,N80 钢的平均腐蚀速率为 0.007 1 mm/a,试片清洗后无均匀腐蚀及点蚀痕迹,表面呈现金属光泽,该复配类缓蚀剂耐高温性能良好,缓蚀性能优异.

Abstract

In order to verify the corrosion inhibition performance of phosphate ester under high temperature and aerobic condition,a polyethylene glycol phosphate ester was synthe-sized by using polyethylene glycol(PEG400),phenol,n-octanol and P2O5 as raw materials,and a quinoline phosphate compound corrosion inhibitor was formed by combining polyethy-lene glycol phosphate ester with benzyl chloride quaternary ammonium salts.The corrosion inhibition effect of quinoline phosphate compound corrosion inhibitor was studied by electro-chemical evaluation,and the protection effect of corrosion inhibitor under high temperature and aerobic condition was studied by high temperature autoclave evaluation.The results show that the average corrosion rate of N80 steel is 0.007 1 mm/a under the condition of 180℃,2 MPa CO2+0.02 MPa O2,there is no uniform corrosion and pitting trace after clean-ing,and the surface shows metallic luster.The compound corrosion inhibitor has good high temperature resistance and excellent corrosion inhibition performance.

关键词

磷酸酯/喹啉/高温/缓蚀剂

Key words

phosphate ester/quinoline/high temperature/corrosion inhibitor

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出版年

2024
石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
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