石油化工应用2024,Vol.43Issue(12) :110-113.DOI:10.3969/j.issn.1673-5285.2024.12.023

活性炭对水中吡虫啉的吸附性能研究

Study of adsorption properties of activated carbon on imidacloprid in water

孙磊 杨嘉伟 王阳阳 王嘉宁 杨柳
石油化工应用2024,Vol.43Issue(12) :110-113.DOI:10.3969/j.issn.1673-5285.2024.12.023

活性炭对水中吡虫啉的吸附性能研究

Study of adsorption properties of activated carbon on imidacloprid in water

孙磊 1杨嘉伟 1王阳阳 1王嘉宁 1杨柳1
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作者信息

  • 1. 兰州交通大学环境与市政工程学院,甘肃 兰州 730070
  • 折叠

摘要

以性能优良易于获得的活性炭(AC)为吸附剂,用于吸附去除水中的吡虫啉(IMI).在 15℃下,其最大吸附量为324.93 mg/g.由表征分析可知,AC具有良好的孔隙结构,其比表面积为 160.5 m2/g.吸附动力学、等温线及热力学分析表明,其对IMI的吸附过程包括化学吸附和物理吸附,是一个自发、放热、随机性递增的过程,推断AC对IMI的吸附机理主要是孔隙填充、含氧官能团络合(氢键和范德华力)和π-π共轭作用.

Abstract

Activated carbon(AC),which is easily available with good properties,was used as an adsorbent for the adsorption and removal of imidacloprid(IMI)from water.The maxi-mum adsorption capacity was 324.93 mg/g at 15℃.From the characterization analysis,it was found that AC has a good pore structure with a specific surface area of 160.5 m2/g.From the adsorption kinetics,isotherm and thermodynamic analyses,its adsorption process of imi-dacloprid included chemisorption and physisorption,which was a spontaneous,exothermic and stoichiometric incremental process,and it was deduced that the adsorption mechanism of AC on IMI was mainly the pore-filling,the complexation of oxygen-containing functional groups(hydrogen bonding and van der Waals'force)and the π-π conjugation effect.

关键词

活性炭/吸附/吡虫啉

Key words

activated carbon/adsorption/imidacloprid

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出版年

2024
石油化工应用
宁夏化工学会

石油化工应用

影响因子:0.276
ISSN:1673-5285
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