首页|基于响应面法的微电解活化过硫酸盐降解苯酚研究

基于响应面法的微电解活化过硫酸盐降解苯酚研究

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目的 优化微电解活化过硫酸盐氧化处理苯酚废水体系的工艺条件,提高废水处理效果.方法 构建微电解活化过硫酸盐氧化降解体系,采用响应面法分析过硫酸盐浓度、初始pH值和反应温度对苯酚废水降解效果的影响,使用模型确定最佳工艺参数.结果 三个因素对苯酚降解率均有较显著影响,显著性由大到小依次为反应温度、过硫酸盐浓度、初始pH值;模拟得出的最佳工艺条件:过硫酸盐浓度为15.98 mmol/L、初始pH值为2.78、反应温度为74.73 ℃,并且模拟预测结果与试验数据非常接近.结论 该模型可以较为准确地预测微电解活化过硫酸盐降解苯酚废水的最佳反应条件与降解率.
Degradation of Phenol by Micro-electrolysis Activated Persulfate Based on Response Surface Method
The process parameters and the removal efficiency of micro-electrolysis activated persulfate in phenol wastewater treatment system were studied and optimized,so as to efficiently degrade phenol wastewater.The micro-electrolysis activated persulfate system was constructed.The effect of the persulfate concentration,initial pH value and reaction temperature on phenol degradation rate was analyzed by the response surface method(RSM).The parameters of micro-electrolysis activated persulfate process for phenol degradation were optimized by the fitted model of RSM.The results showed that all the dependent variables had significant effects on the response value,and the order of dominance from high to low was reaction temperature,persulfate concentration,and initial pH value.The optimal process conditions were as follows:persulfate concentration was 15.98 mmol/L,initial pH value was 2.78,and reaction temperature was 74.73 ℃.The experimental results were consistent with the predicted values.Persulfate concentration and reaction temperature have obvious effects on phenol degradation rate,and this fitted model of RSM can accurately predict the optimal reaction conditions and degradation rate of phenol wastewater by micro-electrolysis activated persulfate.

persulfatemicro-electrolysisresponse surface methodphenol

胡俊生、李嘉宝、王海曼、张添淇

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沈阳建筑大学市政与环境工程学院,辽宁沈阳 110168

过硫酸盐 微电解 响应曲面法 苯酚

国家自然科学基金项目

51908377

2024

沈阳建筑大学学报(自然科学版)
沈阳建筑大学

沈阳建筑大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.697
ISSN:2095-1922
年,卷(期):2024.40(3)
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