首页|原油沥青质含量对纳米颗粒-十二烷基硫酸钠发泡二氧化碳泡沫稳定性的影响

原油沥青质含量对纳米颗粒-十二烷基硫酸钠发泡二氧化碳泡沫稳定性的影响

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采用十二烷基硫酸钠(SDS)表面活性剂和SiO2纳米颗粒作为发泡体系,在不同原油沥青质含量下进行泡沫稳定性实验,测量CO2泡沫半衰期;采用扫描电子显微图像、紫外分光光度法测试和Zeta电位测量,分析沥青质降低CO2泡沫稳定性的机理.研究表明:当合成油与发泡体系质量比为1∶9时,合成油沥青质质量分数从0增至15%,SDS稳定泡沫半衰期从751 s减少至239 s,SDS-SiO2稳定泡沫半衰期从912 s缩短至298 s;当合成油与发泡体系质量比为2∶8时,随着沥青质质量分数增大,SDS稳定泡沫半衰期从526 s缩短至171 s,SDS-SiO2稳定泡沫半衰期从660 s缩短至205 s.由于沥青质与SDS和SiO2纳米颗粒在水相中的相互作用,Zeta电位绝对值减小,颗粒表面电荷降低,导致薄液膜两侧界面之间的排斥力减小,从而破坏泡沫稳定性.
Experimental investigation of the effects of oil asphaltene content on CO2 foam stability in the presence of nanoparticles and sodium dodecyl sulfate
Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO2 foam was measured.The mechanism of foam stability reduction in the presence of asphaltene was analyzed by scanning electron microscope(SEM),UV adsorption spectrophotometric concentration measurement and Zeta potential measurement.When the mass ratio of synthetic oil to foam-formation suspension was 1∶9 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 751 s to 239 s,and the half-life of SDS/silica-stabilized foams decreased from 912 s to 298 s.When the mass ratio of synthetic oil to foam-formation suspension was 2:8 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 526 s to 171 s,and the half-life of SDS/silica-stabilized foams decreased from 660 s to 205 s.In addition,due to asphaltene-SDS/silica interaction in the aqueous phase,the absolute value of Zeta potential decreases,and the surface charges of particles reduce,leading to the reduction of repulsive forces between two interfaces of thin liquid film,which in turn,damages the foam stability.

CO2 foamfoam stabilityasphaltenesilica nanoparticlesodium dodecyl sulfate(SDS)repulsive forcessurface chargesZeta potential

SADEGHI Hossein、KHAZ'ALI Ali Reza、MOHAMMADI Mohsen

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伊斯法罕理工大学化学工程系,伊斯法罕84156-83111,伊朗

丹麦技术大学丹麦海洋工程技术中心,灵比2800,丹麦

CO2泡沫 泡沫稳定性 沥青质 二氧化硅纳米颗粒 十二烷基硫酸钠(SDS) 排斥力 表面电荷 Zeta电位

2024

石油勘探与开发
中国石油天然气股份有限公司勘探开发研究院 中国石油集团科学技术研究院

石油勘探与开发

CSTPCD北大核心
影响因子:4.977
ISSN:1000-0747
年,卷(期):2024.51(1)
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