首页|Design of dual-functional protic porous ionic liquids for boosting selective extractive desulfurization
Design of dual-functional protic porous ionic liquids for boosting selective extractive desulfurization
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NETL
NSTL
万方数据
Porous ionic liquids have demonstrated excellent performance in the field of separation,attributed to their high specific surface area and efficient mass transfer.Herein,task-specific protic porous ionic liquids(PPILs)were prepared by employing a novel one-step coupling neutralization reaction strategy for extractive desulfurization.The single-extraction efficiency of PPILs reached 75.0％for dibenzothiophene.Moreover,adding aromatic hydrocarbon interferents resulted in a slight decrease in the extraction ef-ficiency of PPILs(from 45.2％to 37.3％,37.9％,and 33.5％),indicating the excellent extraction selectivity of PPILs.The experimental measurements and density functional theory calculations reveal that the surface channels of porous structures can selectively capture dibenzothiophene by the stronger electrophilicity(Eint(Hs surface channel/DBT)=-39.8 kcal mol-1),and the multiple extraction sites of ion pairs can effectively enrich and transport dibenzothiophene from the oil phase into PPILs through π…π,C-H…π and hydrogen bonds interactions.Furthermore,this straightforward synthetic strategy can be employed in preparing porous liquids,offering new possibilities for synthesizing PPILs with tailored functionalities.
Protic porous ionic liquidsExtractive desulfurizationSelectivityDensity functional theory
NETL
NSTL
万方数据
