沈阳师范大学学报(自然科学版)2024,Vol.42Issue(2) :180-185.DOI:10.3969/j.issn.1673-5862.2024.02.013

多晶钙钛矿材料的制备及其性能表征

Preparation and characterization of polycrystalline perovskite materials

于吉 罗寅先 田宁 谭雯竹 郑若宁 王诚源 屈燕梅 黄永涛
沈阳师范大学学报(自然科学版)2024,Vol.42Issue(2) :180-185.DOI:10.3969/j.issn.1673-5862.2024.02.013

多晶钙钛矿材料的制备及其性能表征

Preparation and characterization of polycrystalline perovskite materials

于吉 1罗寅先 1田宁 1谭雯竹 1郑若宁 1王诚源 1屈燕梅 1黄永涛1
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作者信息

  • 1. 沈阳师范大学 物理科学与技术学院,沈阳 110034
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摘要

金属卤化物钙钛矿由于具有较多的优点而有望成为下一代直接X射线探测器的候选材料.目前报道的钙钛矿基射线探测器大多以单晶材料为主,单晶材料往往生长条件严苛、生长过程不可控,并且制备大面积高质量钙钛矿单晶材料仍面临巨大挑战.多晶钙钛矿材料制备工艺简单、周期短,且被广泛应用于光电领域.但在宏观尺度上制备大面积高质量的钙钛矿多晶材料也面临着诸多问题.在此,分别通过机械热压制和浆料刮涂的方法制备尺寸可控的(CH3NH3)3Bi2I9多晶片和CH3NH3PbI3多晶厚膜,分别对它们的微观形貌、晶体结构和电学性质等进行了表征.结果表明,通过热压法和浆料刮涂法制备的(CH3NH3)3Bi2I9多晶片和CH3NH3PbI3多晶厚膜具有较高的晶体质量、致密性和较好的电学性质.

Abstract

Lead-free perovskite has been proved to be an excellent candidate material for the next generation of bio-friendly direct X-ray detectors due to its many advantages.At present,most of the reported perovskite-based ray detectors are mainly single crystal materials.Single crystal materials often have harsh growth conditions and uncontrollable growth processes,and the preparation of large-area high-quality perovskite single crystal materials still faces great challenges.Polycrystalline perovskite materials with simple preparation processes and short cycles are also widely used in the field of optoelectronics.However,the preparation of large-area high-quality perovskite polycrystalline materials on a macro scale still faces great challenges.Here,(CH3NH3)3 Bi2I9 polycrystalline wafers and CH3NH3PbI3 polycrystalline thick films with controllable size were prepared by mechanical hot pressing and slurry coating,respectively.Their microstructure,crystal structure and electrical properties were characterized.The results show that the(CH3 NH3)3 Bi2I9 polycrystalline wafer and CH3NH3PbI3 polycrystalline thick film prepared by hot pressing method and slurry coating method have high crystal quality,compactness and good electrical properties.

关键词

金属卤化物钙钛矿/X射线探测器/多晶片/多晶厚膜

Key words

metal halide perovskites/X-ray detectors/polycrystalline wafers/polycrystalline thick film

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基金项目

辽宁省教育厅高校基本科研项目(LJKMZ20221470)

出版年

2024
沈阳师范大学学报(自然科学版)
沈阳师范大学

沈阳师范大学学报(自然科学版)

CSTPCD
影响因子:0.591
ISSN:1673-5862
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