首页|基于原子层沉积基底的液体分子表面增强拉曼作用距离分析

基于原子层沉积基底的液体分子表面增强拉曼作用距离分析

Distance analysis of surface-enhanced raman scattering of liquid molecules based on atomic layer deposition substrate

扫码查看
目的 使用原子层沉积(atomic layer deposition,ALD)技术探究表面增强拉曼(surface enhancement of raman scattering,SERS)效应强度随探针分子与增强表面距离的变化.方法 研究使用ALD技术在SERS表面沉积不同厚度的二维材料以阻隔拉曼探针分子与表面,从而探究不同作用距离对于该表面SERS效应的削弱作用,并研究探针分子拉曼光谱强度的变化;以银-硅组合作为SERS基底,以 10-4 mol/L浓度结晶紫水溶液作为拉曼探针进行了不同厚度二维材料下的SERS效应探究实验.结果 532 nm激光波长下的液体SERS光谱强度大体上随二维材料厚度的增大而减弱.结论 5nm厚度是其作用极限距离.
Objective The aim of this study is to investigate the variation of SERS effect intensity with the distance between probe molecules and the enhanced surface using atomic layer deposition(ALD)technology.Methods The study used ALD technology to deposit two-dimensional materials with different thicknesses on the surface of SERS to block raman probe molecules from the surface,exploring the weakening effect of different interaction distances on the SERS effect of the surface,and studying the changes in raman spectral intensity of probe molecules;the study used a silver-silicon combination as the SERS substrate,and a crystal violet aqueous solution with a concentration of 10-4 mol/L as a raman probe to conduct SERS effect exploration experiments on two-dimensional materials with different thicknesses.Results The final experimental results prove that the liquid SERS spectral intensity at the 532 nm laser wavelength generally weakens with the increase in the thickness of the two-dimensional material.Conclusion 5 nm thickness is its limiting distance.

SERSALDdata analysisraman probeoperating distance

常玉玺、朱鹏帅、李享

展开 >

中国船舶集团公司第七〇三研究所无锡分部,无锡 211400

表面增强拉曼 原子层沉积 数据分析 拉曼探针 作用距离

2024

实验室检验
中国检验检测学会

实验室检验

ISSN:2097-261X
年,卷(期):2024.2(2)
  • 15