沈阳药科大学学报2024,Vol.41Issue(2) :161-167.DOI:10.14066/j.cnki.cn21-1349/r.2023.0206

微波辅助合成CNB/MIL光催化降解水中罗丹明B

Microwave-assisted synthesis of CNB/MIL for photocatalytic degradation of rhodamine B in water

张梦丹 张聪璐
沈阳药科大学学报2024,Vol.41Issue(2) :161-167.DOI:10.14066/j.cnki.cn21-1349/r.2023.0206

微波辅助合成CNB/MIL光催化降解水中罗丹明B

Microwave-assisted synthesis of CNB/MIL for photocatalytic degradation of rhodamine B in water

张梦丹 1张聪璐1
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作者信息

  • 1. 沈阳药科大学制药工程学院,辽宁本溪 117004
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摘要

目的 构建可见光响应的异质结光催化材料,高效降解水中有机染料.方法 通过微波辅助合成体相氮化碳(carbon nitride bulk,CNB)和金属有机骨架材料MIL-100(Fe)的异质结(CNB/MIL).结果 表征分析证实CNB/MIL成功合成.在可见光下,90 min内,15 mg CNB/MIL对体积为50 mL、质量浓度为10 mg·L-1的罗丹明B(RhB)的降解率接近100%.降解机理研究表明,OH是光催化过程中的主要活性物种.结论 氮化碳与MIL复合,能够起到协同作用,提高材料的可见光响应能力,此外,利用微波辅助法合成可大大缩短材料合成时间,节省能源.

Abstract

Objective To construct a visible light responsive heterojunction photocatalyst material for efficient degradation of organic dyes in water.Methods Carbon nitride bulk(CNB)and metal-organic framework(MIL-100(Fe))heterojunction(CNB/MIL)were synthesized by microwave assisted method.Results The characterization analysis confirmed that CNB/MIL was successfully synthesized.Under visible light,the degradation rate of 15 mg CNB/MIL to rhodamine B(RhB)with a volume of 50 mL and a concentration of 10 mg·L-1 is close to 100%within 90 minutes.The study of degradation mechanism shows that·OH is the main active species in the photocatalytic process.Conclusions Carbon nitride combined with MIL can play a synergistic role in improving the visible light response of the material.In addition,using micro wave assisted synthesis can greatly shorten the synthesis time and save energy.

关键词

氮化碳/金属有机骨架材料/光催化降解/罗丹明B

Key words

carbon nitride/metal-organic framework material/photocatalytic degradation/rhodamine B

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基金项目

辽宁省教育厅科学研究面上项目(LJKZ0910)

沈阳药科大学中青年教师事业发展支持计划中青年骨干人才培育计划(ZQN2021026)

出版年

2024
沈阳药科大学学报
沈阳药科大学

沈阳药科大学学报

CSTPCDCSCD
影响因子:0.604
ISSN:1006-2858
参考文献量20
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