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煤阻燃体系应用开发研究

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稠环芳烃含量高的煤具有潜在的炭化阻燃作用。选用聚磷酸铵、分子筛、酚醛树脂等提高煤的阻燃作用。管式裂解炉炭化实验、氧指数法和热失重法测试结果显示,APP改善了煤的炭化能力,而分子筛、尼龙、酚醛和沥青可进一步提高煤/APP的炭化阻燃作用。锥形量热法得出,煤/APP阻燃体系的阻燃作用达到甚至优于经典膨胀阻燃体系的作用,而在成本与疏水性方面优于经典膨胀阻燃体系。扫描电镜结果表明,煤/APP阻燃体系中的各组分之间以及与聚合物基体之间的混容性仍需进一步提高。
Research and Development of Coal Flame Retardant System
Coal, a highly fused ring aromatic compound, is a potential charring and flame retardant. Ammonium polyphosphate (APP), zeolite, and thermoplastic phenolic resin were used to better the coal carbonization flame retardant efficiency. The results of the charring of the tubular pyrolysis furnace, the oxygen index measurement, and thermogravimetric analysis show that, APP can improve the charring of coal, while molecular sieves, nylon, phenolic resin and asphalt can further upgrade the carbonization of coal/APP flame retardant system. Unexpectedly, the foaming agents, melamine didn't make a significant improvement in the coal/APP flame retardant. Cone calorimetry presents exciting findings, the flame retardancy of the coal/APP system is almost same as that of the traditional flame retardant system,but the coal/APP system prevails in the costs and hydrophobicity as compared with the traditional system. Unfortunately, the compatibility both among flame retardant components and between the flame retardant and polymer matrix should be enhanced.

coalflame retardantoxygen indexcharringmorphology

赵云、吴雪云、莫晓杰、石小丽、朱新生

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苏州大学纺织与服装工程学院,江苏苏州215021

苏州大学材料与化学化工部,江苏苏州215123

阻燃 氧指数 炭化 形态

苏州大学2010年江苏省大学生实践创新训练计划项目

5731506810

2012

苏州大学学报(工科版)
苏州大学

苏州大学学报(工科版)

影响因子:0.256
ISSN:1673-047X
年,卷(期):2012.32(3)
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