唐山师范学院学报2024,Vol.46Issue(6) :13-18.DOI:10.3969/j.issn.1009-9115.2024.06.003

磁性银掺杂TiO2纳米管的合成及抗菌活性

Synthesis of Magnetic TiO2 Nanotubes Doped with Ag+and the Antibacterial Activity

罗瑢泽 张会利 陈亚欣 丁雨杰 张小乐
唐山师范学院学报2024,Vol.46Issue(6) :13-18.DOI:10.3969/j.issn.1009-9115.2024.06.003

磁性银掺杂TiO2纳米管的合成及抗菌活性

Synthesis of Magnetic TiO2 Nanotubes Doped with Ag+and the Antibacterial Activity

罗瑢泽 1张会利 2陈亚欣 1丁雨杰 1张小乐1
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作者信息

  • 1. 华北理工大学生命科学学院,河北唐山 063210
  • 2. 唐山旭阳化工有限公司,河北唐山 063606
  • 折叠

摘要

利用溶胶凝胶法合成了银掺杂的TiO2纳米颗粒,然后在浓碱液中通过水热反应卷曲成纳米管,最后采用共沉淀法在纳米管上负载磁性Fe3O4颗粒,制备了一种磁性银掺杂的TiO2纳米管复合材料.合成的复合材料中,银掺杂TiO2纳米管的平均直径约为10 nm,其上负载着10 nm左右的Fe3O4颗粒;该材料对大肠杆菌和缓慢葡萄球菌均具有良好的抗菌活性,最小抑制浓度和最小杀菌浓度都分别为100 mg·L-1和400 mg·L-1;62.5 mg·L-1的复合材料处理240 min后可达95%以上的杀菌率.同时,该复合材料具有超顺磁性和较高的饱和磁通量(17.26 emu·g-1),处理之后可方便地进行磁分离回收,以便重复使用,节约了处理成本.

Abstract

Silver-doped TiO2 nanoparticles were synthesized using sol-gel method and were curled into nanotubes through hydrothermal reaction under concentrated alkaline condition.Subsequently,magnetic Fe3O4 particles were loaded onto the nanotubes by a co-precipitation method to form magnetic TiO2 nano-tubes doped with Ag+.The Ag+doped TiO2 nanotubes,with an average diameter of about 10 nm,were anchored with plenty of Fe3O4 particles of 10nm in diameter.The composite exhibited high antibacterial a-bility toward Escherichia coli and Staphylococcus lentus,with low minimum inhibitory concentration(100 mg·L-1)and minimum bactericidal concentration(400 mg·L-1)for both strains.Bactericidal ratio of higher than 95%could be achieved after treatment with 65 mg·L-1 of the composite for 4h.Additionally,the composite,with superparamagnetism and a high saturation magnetization of 17.26 emu·g-1,can be easily recovered after treatment,which greatly reduces the processing cost and facilitates reuse.

关键词

TiO2纳米管/银离子掺杂/磁分离能力/合成/抗菌活性

Key words

TiO2 nanotubes/silver ions doping/magnetic separation ability/synthesis/antibacterial activity

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出版年

2024
唐山师范学院学报
唐山师范学院

唐山师范学院学报

影响因子:0.204
ISSN:1009-9115
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