首页|低温快烧Pr-Ce-ZrSiO4黄色色釉的制备研究

低温快烧Pr-Ce-ZrSiO4黄色色釉的制备研究

Preparation of Pr-Ce-ZrSiO4 Yellow Colour Glaze with Low Temperature Fast Firing

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笔者采用正交试验法,优化无熔块基釉配比,并以此为基础,加入固相法合成 Pr-Ce-ZrSiO4 黄色陶瓷色料,制备一种适应于低温快烧的建筑陶瓷黄色色釉,研究煅烧温度、Pr/Ce 摩尔比对于色釉呈色的影响.实验结果表明,基釉配比为硼钙石∶锂长石∶石英∶萤石∶BaCO3∶SrCO3=15∶52∶20∶4∶5∶8 时,能够获得良好的釉面质量与光泽度;而对于Pr-Ce-ZrSiO4 黄色色料,在 1 200℃的煅烧温度下,Pr4+能够最大限度进入到 ZrSiO4 晶体中,使得釉面产生良好的着色效果;当Pr/Ce摩尔比为 1∶0.55 时,Ce4+与Pr4+能够取代Zr4+形成有限固熔体,降低色釉釉面的绿色色调,使得釉面色度由黄色过渡到橙黄色.
An orthogonal test method was employed to improve compositions of the raw material glaze.Subsequently,Pr-Ce-ZrSiO4 yellow ceramic pigment was incorporated into the solid phase method to synthesise a yellow glaze for building ceramics,optimised for low-temperature fast firing.Additionally,the effects of calcination temperature and Pr/Ce molar ratio on the color presentation of color glazes were investigated.The experimental results demonstrate that when the ratio of the base glaze is colemanite∶lithium feldspar∶quartz∶fluorite,the following outcomes are produced.BaCO3∶The Sr-CO3 ratio of 15∶52∶20∶4∶5∶8 allows for the production of a high-quality glaze with excellent gloss.The calcination temperature of 1 200℃is optimal for the Pr-Ce-ZrSiO4 yellow color pigment,as it allows for maximal penetration of Pr4+ions into ZrSiO4 crystals,resulting in superior glaze coloring.The glaze exhibits an optimal coloring effect when the Pr/Ce molar ratio is 1∶0.55.At this ratio,Ce4+and Pr4+can replace Zr4+to form a limited solid melt,reducing the green hue of the color glaze.This results in a transition from yellow to orange-yellow in the glaze color.

Yellow color glazePr-Ce dopingSolid phase method

查越、刘群海、徐望辉、黄弘、胡海泉、黄域之、谢言之、张小娜、邵宇佳

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中国轻工业陶瓷研究所 江西 景德镇 333000

景德镇陶瓷大学 江西 景德镇 333000

佛山市明诺制釉有限公司 广东 佛山 528000

景德镇艺术职业大学 江西 景德镇 333000

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黄色色釉 Pr-Ce掺杂 固相法

中央引导地方科技发展资金

20231ZDE04022

2024

陶瓷
咸阳陶瓷研究设计院

陶瓷

影响因子:0.192
ISSN:1002-2872
年,卷(期):2024.(9)