陶瓷学报2024,Vol.45Issue(1) :72-88.DOI:10.13957/j.cnki.tcxb.2024.01.006

固体氧化物燃料电池Ni基阳极抗积碳的研究进展

Research Progress in Coking Resistance of Ni-based Anodes for Solid Oxide Fuel Cells

曹希文 罗凌虹 曾小军 王乐莹 徐序 刘邵帅 程亮
陶瓷学报2024,Vol.45Issue(1) :72-88.DOI:10.13957/j.cnki.tcxb.2024.01.006

固体氧化物燃料电池Ni基阳极抗积碳的研究进展

Research Progress in Coking Resistance of Ni-based Anodes for Solid Oxide Fuel Cells

曹希文 1罗凌虹 2曾小军 2王乐莹 2徐序 2刘邵帅 2程亮2
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作者信息

  • 1. 景德镇陶瓷大学,江西景德镇 333403;江西工业工程职业技术学院,江西萍乡 337000
  • 2. 景德镇陶瓷大学,江西景德镇 333403
  • 折叠

摘要

固体氧化物燃料电池(SOFC)是一种缓解能源危机的新兴能源技术,具有效率高、可持续、无污染等优势.Ni基金属陶瓷由于兼具高电子电导、高离子电导和对碳氢燃料极佳的催化活性等优势,成为目前商业化SOFC阳极材料的最佳选择.然而,Ni基阳极SOFC在使用含碳燃料时,由于碳沉积而容易导致其失活,造成电池性能衰减.针对于此,首先,分析Ni基阳极在含碳燃料中积碳的机理,阐明Ni基阳极积碳的原因、过程、类型以及危害,并介绍探测积碳常用的表征方法;然后,归纳总结当前国内外对于改善Ni基阳极抗积碳的机制和策略;最后,对Ni基阳极抗积碳策略的发展方向提出展望.

Abstract

Solid oxide fuel cell(SOFC)is an emerging energy technology to alleviate the energy crisis,which has the advantages of high efficiency,sustainability and pollution-free.Ni-based cermets have become the most promising choice for commercial SOFC anode materials,due to their high electronic conductivity,high ionic conductivity and excellent catalytic activity for hydrocarbon fuels.However,when carbon-containing fuels are used for Ni-based anode SOFC,it is easy to deactivate due to carbon deposition,resulting in battery performance degradation.In view of this,the mechanism of Ni-based anode carbon deposition in carbon-containing fuels is firstly analyzed.Then,the causes,processes,types and hazards of Ni-based anodic carbon deposition are clarified and the common characterization methods for carbon deposition are introduced.Secondly,the mechanisms and strategies of Ni-based anodes at home and abroad to improve the coking resistance are summarized.Finally,prospects for the development direction of carbon resistance strategy for Ni-based anodes are proposed.

关键词

固体氧化物燃料电池/Ni基阳极/金属陶瓷/抗积碳

Key words

solid oxide fuel cell/Ni-based anode/cermet/coking resistance

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基金项目

国家自然科学基金(51762026)

国家自然科学基金(51802132)

江西省自然科学基金重点项目(20224ACB204010)

江西省教育厅科技落地计划(KJLD13072)

江西省教育厅科技项目(GJJ2201009)

江西省教育厅科技项目(GJJ2201010)

出版年

2024
陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
被引量1
参考文献量103
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