陶瓷学报2024,Vol.45Issue(1) :89-96.DOI:10.13957/j.cnki.tcxb.2024.01.007

CoZn@NC与CuS的强耦合界面构建及其超薄电磁波吸收

Construction of Strong Coupling Interface between CoZn@NC and CuS for Ultrathin Electromagnetic Wave Absorption

黄惠中 李博 赵超 蒋肖 曾小军
陶瓷学报2024,Vol.45Issue(1) :89-96.DOI:10.13957/j.cnki.tcxb.2024.01.007

CoZn@NC与CuS的强耦合界面构建及其超薄电磁波吸收

Construction of Strong Coupling Interface between CoZn@NC and CuS for Ultrathin Electromagnetic Wave Absorption

黄惠中 1李博 1赵超 1蒋肖 1曾小军1
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作者信息

  • 1. 景德镇陶瓷大学材料科学与工程学院,江西景德镇 333403
  • 折叠

摘要

电磁波的污染促使高性能电磁波(EMW)吸收剂的发展,然而单一组分的吸波材料不能满足目前的性能要求.因此,多组分复合材料是目前的研究焦点.该研究巧妙地设计CoZn基金属有机骨架(CoZn-ZIF-L)纳米片,并转化为氮掺杂的碳包裹的CoZn纳米颗粒(CoZn@NC).随后,利用水热工艺在CoZn@NC表面复合超小的CuS纳米颗粒,构建强界面耦合结构,有效地将CoZn@NC与CuS的介电性能优势结合起来.实验结果表明,优化后的异质结构显著提高了电磁波吸收能力.CoZn@NC/CuS异质结构表现出优异的EMW吸收性能,其反射损耗(RL)达到-56.2 dB,匹配厚度仅为1.46 mm,有效吸收频带宽(EAB,RL<-10 dB)达4.13 GHz.该工作为设计一种强界面耦合的高性能EMW吸收材料提供了一条高效的思路.

Abstract

Pollution from electromagnetic waves has prompted the development of high-performance electromagnetic wave(EMW)absorbers.However,single-component absorption materials cannot meet current performance requirements.Therefore,multi-component composites become the focus of research.Here,CoZn-based metal organic framework(CoZn-ZIF-L)nanosheets are synthesized and transformed into nitrogen-doped carbon-wrapped CoZn nanoparticles(CoZn@NC).Subsequently,a hydrothermal process was used to compound ultrasmall CuS nanoparticles on surface of the CoZn@NC to construct a strong interface coupling structure,effectively combining the dielectric properties of CoZn@NC and CuS.It is experimentally demonstrated that the optimized heterostructure exhibited significantly enhanced EMW absorption capacity,with a reflection loss(RL)of-56.2 dB,a matching thickness of only 1.46 mm,and an effective absorption bandwidth(EAB,RL<-10 dB)of 3.6 GHz.This work provides an efficient way to design high-performance EMW absorption materials with strong interface coupling.

关键词

CuS/超薄匹配厚度/界面耦合/介电损耗/电磁波吸收

Key words

CuS/ultrathin matching thickness/interface coupling/dielectric loss/electromagnetic wave absorption

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基金项目

国家自然科学基金(22269010)

江西省自然科学基金(20224BAB214021)

Major Research Program of Jingdezhen Ceramic Industry(2023ZDGG002)

出版年

2024
陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
被引量1
参考文献量24
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