首页|CoZn@NC与CuS的强耦合界面构建及其超薄电磁波吸收

CoZn@NC与CuS的强耦合界面构建及其超薄电磁波吸收

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电磁波的污染促使高性能电磁波(EMW)吸收剂的发展,然而单一组分的吸波材料不能满足目前的性能要求.因此,多组分复合材料是目前的研究焦点.该研究巧妙地设计CoZn基金属有机骨架(CoZn-ZIF-L)纳米片,并转化为氮掺杂的碳包裹的CoZn纳米颗粒(CoZn@NC).随后,利用水热工艺在CoZn@NC表面复合超小的CuS纳米颗粒,构建强界面耦合结构,有效地将CoZn@NC与CuS的介电性能优势结合起来.实验结果表明,优化后的异质结构显著提高了电磁波吸收能力.CoZn@NC/CuS异质结构表现出优异的EMW吸收性能,其反射损耗(RL)达到-56.2 dB,匹配厚度仅为1.46 mm,有效吸收频带宽(EAB,RL<-10 dB)达4.13 GHz.该工作为设计一种强界面耦合的高性能EMW吸收材料提供了一条高效的思路.
Construction of Strong Coupling Interface between CoZn@NC and CuS for Ultrathin Electromagnetic Wave Absorption
Pollution from electromagnetic waves has prompted the development of high-performance electromagnetic wave(EMW)absorbers.However,single-component absorption materials cannot meet current performance requirements.Therefore,multi-component composites become the focus of research.Here,CoZn-based metal organic framework(CoZn-ZIF-L)nanosheets are synthesized and transformed into nitrogen-doped carbon-wrapped CoZn nanoparticles(CoZn@NC).Subsequently,a hydrothermal process was used to compound ultrasmall CuS nanoparticles on surface of the CoZn@NC to construct a strong interface coupling structure,effectively combining the dielectric properties of CoZn@NC and CuS.It is experimentally demonstrated that the optimized heterostructure exhibited significantly enhanced EMW absorption capacity,with a reflection loss(RL)of-56.2 dB,a matching thickness of only 1.46 mm,and an effective absorption bandwidth(EAB,RL<-10 dB)of 3.6 GHz.This work provides an efficient way to design high-performance EMW absorption materials with strong interface coupling.

CuSultrathin matching thicknessinterface couplingdielectric losselectromagnetic wave absorption

黄惠中、李博、赵超、蒋肖、曾小军

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景德镇陶瓷大学材料科学与工程学院,江西景德镇 333403

CuS 超薄匹配厚度 界面耦合 介电损耗 电磁波吸收

国家自然科学基金江西省自然科学基金Major Research Program of Jingdezhen Ceramic Industry

2226901020224BAB2140212023ZDGG002

2024

陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
年,卷(期):2024.45(1)
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