陶瓷学报2024,Vol.45Issue(1) :117-124.DOI:10.13957/j.cnki.tcxb.2024.01.011

BaTiO3/g-C3N4复合材料的制备及压电光催化性能研究

Preparation and Piezo-photocatalytic Properties of BaTiO3/g-C3N4 Composites

邢子翱 赵慧珍 庆达 王建省 曾雄丰
陶瓷学报2024,Vol.45Issue(1) :117-124.DOI:10.13957/j.cnki.tcxb.2024.01.011

BaTiO3/g-C3N4复合材料的制备及压电光催化性能研究

Preparation and Piezo-photocatalytic Properties of BaTiO3/g-C3N4 Composites

邢子翱 1赵慧珍 1庆达 1王建省 2曾雄丰2
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作者信息

  • 1. 华北理工大学材料科学与工程学院河北省无机非金属材料实验室,河北唐山 063210
  • 2. 华北理工大学材料科学与工程学院河北省无机非金属材料实验室,河北唐山 063210;河北省(唐山)陶瓷产业技术研究院,河北唐山 063007
  • 折叠

摘要

采用Ba(OH)2·8H2O、TiO2通过水热—煅烧法制备四方相BaTiO3.以三聚氰胺为前驱体,热缩聚法制备g-C3N4.简单研磨制备不同质量分数BaTiO3/g-C3N4压电光催化复合材料.采用X射线衍射(XRD)、扫描电镜(SEM)、紫外—可见漫反射吸收光谱(UV-Vis)对样品结构、形貌、光学性能进行表征.在模拟太阳光与超声波作用下降解罗丹明(RhB),研究了复合材料的压电光催化性能.结果表明:10%BaTiO3/g-C3N4光吸收性能最好,压电光催化性能最优,100 min内对RhB降解率为97.81%,是g-C3N4降解速率的1.48倍.捕获剂实验表明,压电光催化条件下·OH与·O2-为主要活性物种.

Abstract

Tetragonal phase BaTiO3 was prepared by using hydrothermal calcination,with Ba(OH)2·8H2O and TiO2.g-C3N4 was prepared by using thermal condensation method with melamine as precursor.BaTiO3/g-C3N4 piezo-photocatalytic composites with different mass fractions were prepared by simple lapping.Structure,morphology and optical properties of the samples were characterized by using X-ray diffraction(XRD),scanning electron microscopy(SEM)and UV-vis specoscopy.Properties of the composites were studied by simulating the effect of sunlight and ultrasonic wave on degradation of Rhodamine(RhB).It is found that 10%BaTiO3/g-C3N4 has the best visible light absorption performance,whereas the degradation rate of RhB is 97.81%within 100 min,which is 1.48 times that of g-C3N4.The trapping agent experiment showed that OH and·O2 were the main active species under the conditions of piezo-photocatalysis.

关键词

钛酸钡/类石墨相氮化碳/压电光催化

Key words

barium titanate/graphitic phase carbon nitride/piezo-photocatalytic

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基金项目

河北省自然科学基金-钢铁联合基金(E2021209002)

唐山市科技局项目(21130211D)

唐山市科技局项目(22130215H)

华北理工大学大学生创新创业训练计划(X2021224)

出版年

2024
陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
参考文献量28
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