陶瓷学报2024,Vol.45Issue(3) :508-514.DOI:10.13957/j.cnki.tcxb.2024.03.009

莫来石纤维增强氧化物多孔陶瓷及其性能研究

Preparation and Properties of Mullite Fiber Reinforced Oxide Porous Ceramics

黄泽 邓承继 董博 余超 丁军 朱青友 祝洪喜 王奕博
陶瓷学报2024,Vol.45Issue(3) :508-514.DOI:10.13957/j.cnki.tcxb.2024.03.009

莫来石纤维增强氧化物多孔陶瓷及其性能研究

Preparation and Properties of Mullite Fiber Reinforced Oxide Porous Ceramics

黄泽 1邓承继 1董博 1余超 1丁军 1朱青友 1祝洪喜 1王奕博1
扫码查看

作者信息

  • 1. 武汉科技大学省部共建耐火材料与冶金国家重点实验室,湖北武汉 430081
  • 折叠

摘要

以不同规格的粉煤灰漂珠、长石粉和铝矾土粉为主要原料,引入莫来石纤维为增强相,研究莫来石纤维含量对多孔陶瓷材料性能的影响规律及作用机理.结果表明:高温下长石粉中的低熔相能够降低材料的共晶熔点,将基质间的物理界面结合转变为化学结合.样品经1100 ℃烧成后,随着莫来石纤维含量的增加,多孔陶瓷的闭口气孔率增加,而常温耐压强度和体积密度呈现先增大后减小的趋势.当莫来石纤维含量为10 wt.%时,材料具有最佳综合性能,其体积密度为(0.74±0.01)g·cm-3、真气孔率为(72.70±0.58)%,常温下耐压强度为(7.30±0.64)MPa.此外,试样在300 ℃、600 ℃及 900℃下的平均热导率分别为 0.202 W·m-1·K-1、0.214 W·m-1·K-1 及 0.244 W·m-1·K-1.

Abstract

Fly ash cenospheres,feldspar powder and alumina powder with various specifications were utilized as the raw materials and mullite fibers were introduced as a reinforcing phase to fabricate porous ceramics.The effect of mullite fiber on properties of the porous ceramics and the mechanism were studied.It is indicated that the incorporation of low-melting phases from feldspar powder at high temperatures was employed to reduce the eutectic point of materials,transforming the physical interface between the matrix phases into a chemical bond.An increase in mullite fiber content led to rise in closed porosity of the porous ceramics after sintering at 1100 ℃.Simultaneously,room-temperature compressive strength and bulk density initially increased and then decreased with rising content of mullite fiber.Optimal comprehensive performance was achieved when the mullite fiber content was 10 wt.%,resulting in a volume density of(0.74±0.01)g·cm-3,a true porosity of(72.70±0.58)%,and a room-temperature compressive strength of(7.30±0.64)MPa.In addition,average thermal conductivities of the specimens at 300 ℃,600 ℃ and 900 ℃ were 0.202 W·m-1·K-1,0.214 W·m-1·K-1 and 0.244 W·m-1·K-1,respectively.

关键词

粉煤灰漂珠/莫来石纤维/多孔陶瓷材料/液相烧结/高温热导率/力学性能

Key words

fly ash cenosphere/mullite fiber/porous ceramic materials/liquid-phase sintering/high temperature thermal conductivity/mechanical properties

引用本文复制引用

基金项目

湖北省重点研发计划项目(2023BAB106)

国家自然科学基金(U21A2057)

出版年

2024
陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
参考文献量18
段落导航相关论文