陶瓷学报2024,Vol.45Issue(6) :1171-1177.DOI:10.13957/j.cnki.tcxb.2024.06.010

还原氧化石墨烯/碳化硅/碳/环氧树脂复合膜的制备及导热性能研究

Preparation and Thermal Conductivity of rGO/SiC/C/EP Composite Film

张心怡 霍京浩 周波 原晓艳 刘毅 郭守武
陶瓷学报2024,Vol.45Issue(6) :1171-1177.DOI:10.13957/j.cnki.tcxb.2024.06.010

还原氧化石墨烯/碳化硅/碳/环氧树脂复合膜的制备及导热性能研究

Preparation and Thermal Conductivity of rGO/SiC/C/EP Composite Film

张心怡 1霍京浩 1周波 1原晓艳 1刘毅 1郭守武1
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作者信息

  • 1. 陕西科技大学,陕西西安 710021
  • 折叠

摘要

还原氧化石墨烯/聚合物复合材料因其高柔性和高热导率常被用作电子元器件的热界面材料,但还原氧化石墨烯片层易团聚,且热导率存在各向异性,可通过构建复合材料来构建导热通路改善其导热性能.以LED灯为研究对象,通过静电纺丝—高温煅烧法制得还原氧化石墨烯/碳化硅/碳复合材料.与环氧树脂共混得到还原氧化石墨烯/碳化硅/碳复合材料/环氧树脂复合薄膜,研究不同还原氧化石墨烯加入量对复合薄膜导热性能的影响.结果表明:该复合材料具有三维网络结构,还原氧化石墨烯片层插入了碳化硅/碳纳米纤维间,有效防止了还原氧化石墨烯的堆叠问题,且碳化硅/碳纳米纤维在还原氧化石墨烯片层间形成了有效的导热通路,从而提高了材料的热导率.还原氧化石墨烯/碳化硅/碳复合材料/环氧树脂复合薄膜的热导率达到2.097 W·m-1·K-1,表明碳化硅与还原氧化石墨烯复合能够有效提高导热性能.该研究有望为电子器件及其他需要热管理应用的领域提供一种新型导热材料.

Abstract

Reduced graphene oxide(rGO)/polymer composites are often used as thermal interface materials for electronic components because of their high flexibility and high thermal conductivity,but the reduced graphene oxide sheets are easy to agglutinate and the thermal conductivity is anisotropic,and the thermal conductivity can be improved by adding thermal conductive filler to build a thermal conductivity path.The reduced graphene oxide/silicon carbide/carbon composites were prepared by electrospinning and high-temperature calcination with LED lamp as the research object.rGO/SiC/C/EP composite films were prepared by blending with epoxy resin.The effects of different amounts of rGO on thermal conductivity of the composite films were studied.The results show that the composite has a three-dimensional network structure,and the rGO layer is inserted between the SiC/C nanofbers,which effectively prevents the stacking problem of rGO,and the SiC/C nanofibers form an effective thermal conduction path between the rGO laminates,thereby improving the thermal conductivity of the material.The thermal conductivity of rGO/SiC/C/EP-2 composite film reaches 2.097 W·m-1·K-1,indicating that the composite of SiC and rGO can effectively improve the thermal conductivity.This research provides a new thermal conductivity material for electronic devices and other applications requiring thermal management.

关键词

热界面材料/还原氧化石墨烯/碳化硅纳米纤维/环氧树脂/导热性能

Key words

thermal interface material/reduced graphene oxide/SiC nanofibers/epoxy resin/thermal conductivity

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出版年

2024
陶瓷学报
景德镇陶瓷学院

陶瓷学报

CSTPCD北大核心
影响因子:0.7
ISSN:1000-2278
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