钛工业进展2024,Vol.41Issue(5) :17-22.

低成本Ru/Ti电极的制备及析氯性能研究

Research on Preparation and Chlorine Evolution Performance of Low Cost Ru/Ti Electrodes

冯成 杨瑞锋 郭敏 贾波 康轩齐 徐尚元 冯庆
钛工业进展2024,Vol.41Issue(5) :17-22.

低成本Ru/Ti电极的制备及析氯性能研究

Research on Preparation and Chlorine Evolution Performance of Low Cost Ru/Ti Electrodes

冯成 1杨瑞锋 1郭敏 1贾波 1康轩齐 1徐尚元 1冯庆1
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作者信息

  • 1. 西安泰金新能科技股份有限公司,陕西 西安 710021;西北有色金属研究院,陕西 西安 710016
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摘要

为了提高Ru/Ti电极的析氯活性并降低生产成本,采用热分解法制备了不同低成本金属掺杂的Ru/Ti电极,并对其微观形貌、表面结构、电化学性能和析氯性能进行了表征和分析.结果表明,通过引入低成本金属元素能够有效调控Ru/Ti电极的性能,且Mn、Co、La、Ce、In和Bi元素均能降低RuTi X(X代表金属掺杂元素,物质的量比为 3∶7∶2)电极表面裂纹的宽度和深度.其中,RuTiCe电极的表面裂纹宽度最小,析氯析氧电位差值大,其电解产生的有效氯含量高达 254.0 mg/L,具有高析氯选择性.

Abstract

In order to enhance the chlorine evolution activity and decrease production costs,this study employed the thermal decomposition method to fabricate Ru/Ti electrodes doped with various low-cost metal elements.The micro-morphology,surface structure,electrochemical properties,and chlorine evolution performance were characterized and analyzed.The results show that the performance of Ru/Ti electrodes can be effectively regulated by introducing low-cost metal elements,and the doping of Mn,Co,La,Ce,In and Bi elements can decrease the width and depth of surface cracks on the RuTiX(X represents doped metal element,with molar ratio of 3∶7∶2)electrodes.Particularly,the surface cracks on the RuTiCe electrode are the narrowest,and with a significant difference between chlorine and oxygen evolution potentials,its available chlorine concentration reaches as high as 254.0 mg/L,showcasing excellent chlorine evolution selectivity.

关键词

Ru/Ti电极/析氯性能/电催化反应/热分解

Key words

Ru/Ti electrodes/chlorine evolution performance/electrocatalytic reaction/thermal decomposition

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基金项目

陕西技术创新引导计划项目(2022SSPY-06)

出版年

2024
钛工业进展
中国有色金属工业协会钛锆铪分会 西北有色金属研究院

钛工业进展

CSTPCD
影响因子:0.2
ISSN:1009-9964
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