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高碳铬铁冶炼过程影响因素的研究进展

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本文通过总结国内外相关文献,认为影响高碳铬铁冶炼的主要因素为炉料的物理性能、化学性能和化学成分,且炉料的物理性能和化学性能受炉料的化学成分影响.同时,阐述了MgO、Al2O3、SiO2、CaO和碳质还原剂等化学成分对高碳铬铁冶炼的影响,其中碳质还原剂对炉料的电阻率起决定作用;MgO、Al2O3 和SiO2 等则更多影响冶炼时的熔化性、熔点和黏度等参数.本文还分析了各化学成分对铬铁矿还原的影响,其中Fe、FeO、Fe3 O4、SiO2、CaO、NaOH以及硼酸盐等在一定程度上能促进铬铁矿的还原,而MgO则会抑制铬铁矿的还原.此外,归纳总结了镁铝比和炉渣碱度对高碳铬铁冶炼的影响,将镁铝比控制在 1.3~1.9,炉渣碱度不超过 1.4,可以达到降低冶炼电耗、焦耗和提高铬回收率的效果.
RESEARCH ON INFLUENCING FACTORS IN HIGH CARBON FERROCHROME SMELTING PROCESS
The article summarizes relevant literature at home and abroad,and believes that the main factors affecting the smelting of high carbon ferrochrome are the physical properties,chemical properties,and chemical composition of the furnace charge.The physical and chemical properties of the furnace charge are influenced by the its chemical com-position.At the same time,the influence of chemical components such as MgO,Al2O3,SiO2,CaO,and carbon re-ductants on the smelting of high carbon ferrochromium was elaborated,among these,carbon reductants playing a deci-sive role in the electrical resistivity of the furnace charge;while MgO,Al2O3,and SiO2 have a greater impact on pa-rameters such as meltability,melting point,and viscosity during smelting.The article also analyzed the effects of vari-ous chemical components on the chromite reduction,among which Fe,FeO,Fe3 O4,SiO2,CaO,NaOH,and borate can promote its reduction,while MgO can inhibit it.In addition,the effects of MgO/Al2O3 ratio and slag basicity on the smelting of high carbon ferrochrome were summarized.By controlling the MgO/Al2O3 ratio between 1.3 and 1.9 and keeping the basicity not more than 1.4,the smelting power consumption,coke consumption can be reduced and the chromium recovery rate can be raised.

high carbon ferrochromeinfluencing factorresistivitychemical compositionbasicityMgO/Al2O3 ratio

龚嘉珺、王海娟

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北京科技大学冶金与生态工程学院 北京 100083

高碳铬铁 影响因素 电阻率 化学成分 碱度 镁铝比

2024

铁合金
中钢集团吉林铁合金股份有限公司

铁合金

影响因子:0.174
ISSN:1001-1943
年,卷(期):2024.55(1)
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