首页|MnCe-Al2O3球形颗粒的制备及其催化燃烧环己烷性能

MnCe-Al2O3球形颗粒的制备及其催化燃烧环己烷性能

Preparation of MnCe-Al2O3 Spherical Pellets and Their Catalytic Performance in Cyclohexane Combustion

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挥发性有机物(VOCs)的大量排放会导致环境污染和健康危害,催化燃烧是高效降解 VOCs 的重要手段之一.采用海藻酸盐溶胶-凝胶法合成了 MnCe-Al2O3 球形颗粒作为环己烷催化燃烧催化剂,结果表明,Mn 催化剂中适当添加Ce可提高MnOx的分散性,降低催化剂H2-TPR还原温度.催化剂中Mn和Ce摩尔比为 3∶1、煅烧温度650℃时,催化剂催化燃烧环己烷活性最高,可以在 345℃实现环己烷的完全转化.反应 24h 后,催化剂仍显示出几乎 100%的环己烷转化率,表现了良好的催化稳定性.与浸渍法制备的催化剂相比,MnCe-31-Al2O3-650 催化剂活性更高.
The substantial emissions of volatile organic compounds(VOCs)can lead to environmental pollution and health hazards.Catalytic combustion is an efficient method to degrade VOCs.As a catalyst for cyclohexane catalytic combustion,MnCe-Al2O3 spherical pellets were synthesized using the alginate sol-gel method.The results show that adding Ce to Mn catalysts enhances MnOx dispersion and lowers the catalyst's reduction temperature in H2-TPR.The catalyst with a 3∶1 Mn/Ce molar ratio calcined at 650℃showed the highest activity in cyclohexane combustion,thereby achieving complete conversion at 345℃.After 24 h,the catalyst maintained a nearly 100%cyclohexane con-version rate,indicating high stability.The MnCe-31-Al2O3-650 catalyst showed higher activity than those prepared by the impregnation method.

volatile organic compounds(VOCs)MnCe-Al2O3 spherical pelletalginate sol-gel methodcatalytic combustioncyclohexane

尤生萍、付换然、秦璐、王康、王希涛

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天津大学天津膜科学海水淡化重点实验室,天津 300350

天津大学化工学院,天津 300350

挥发性有机物 MnCe-Al2O3球形颗粒 海藻酸盐溶胶-凝胶法 催化燃烧 环己烷

2025

天津大学学报
天津大学

天津大学学报

北大核心
影响因子:0.793
ISSN:0493-2137
年,卷(期):2025.58(2)