首页|NaCl/Na2SO4 混盐溶液纳滤脱盐分质效果研究

NaCl/Na2SO4 混盐溶液纳滤脱盐分质效果研究

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为探究纳滤技术在工业高盐废水处理中的脱盐分质效果,在实验室搭建的纳滤装置上,采用纳滤膜VNF1-4040,研究了NaCl和Na2SO4 混盐溶液的脱盐分质过程,考察了在不同质量浓度比混盐进料条件下膜通量、进料质量浓度、进料温度对纳滤脱盐效果的影响.研究结果表明,在所考察工况条件下,纳滤膜对Na2SO4 始终有着良好的脱除效果,截留率保持在 97.5%以上.对于质量比为 1∶9 NaCl/Na2SO4 混盐,其Na2SO4 截留率均优于相同运行条件下的其它混盐溶液.膜通量越低,进料质量浓度和进料温度越高,NaCl截留率越低,脱盐效果越好.当膜通量、进料质量浓度和进料温度分别为 26 LMH、2 g/L和 10℃时,Na2SO4 截留率最高,分别为 98.41%、98.24%和98.80%.纳滤膜对混盐溶液中NaCl的分质效果较好,产水中NaCl的质量浓度占比保持在96%以上.
Study on Nanofiltration Desalination and Separation for NaCl/Na2SO4 Mixed Salt Solutions
In order to explore the desalination and mass separation effect of nanofiltration technology in industrial high salt wastewater treatment,the nanofiltration membrane VNF1-4040 was used to study the desalination and separation process for NaCl and Na2SO4 mixed salt solutions.The influence of membrane flux,feed concentration and feed temperature on the desalination effect of nanofiltration with different mass concentration ratios was investigated.The results show that the nanofiltration membrane always has the better removal effect on Na2SO4 under the investigated conditions,and the rejection rate of Na2SO4 is higher than 97.5%.When the mass ratio of NaCl/Na2SO4 is 1∶9,it gets the best rejection rate of Na2SO4 compared with other mass ratio in the same environmental conditions.Lower membrane flux,higher feed concentration and feed temperature can lead to the better NaCl rejection rate,which means better desalination effect.When the membrane flux,feed concentration and feed temperature are 26 LMH,2 g/L and 10℃,the rejection rate of Na2SO4 reaches its peak being 98.41%,98.24%and 98.80%,respectively.In this experiment,nanofiltration membrane has a good separation effect on NaCl,and the proportion of NaCl concentration in the produced water remains above 96%.

nanofiltration membranehigh salt wastewaterNaCl/Na2SO4 mixed saltdesalination and separationnega-tive intercept

杜永亮、张光远、苑宏英、赵冲

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天津城建大学 环境与市政工程学院,天津 300384

天津城建大学 天津市水质科学与技术重点实验室,天津 300384

天津城建大学 基础设施防护和环境绿色生物科技国际联合研究中心,天津 300384

纳滤膜 高盐废水 NaCl/Na2SO4 混盐 脱盐分质 负截留

国家重点研发计划政府间国际创新合作专项国家级大学生创新创业训练计划

2019YFE0122400202210792008

2024

天津城建大学学报
天津城市建设学院

天津城建大学学报

影响因子:0.385
ISSN:2095-719X
年,卷(期):2024.30(1)
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