Research progress of metal-organic frameworks(MOFs)based composite proton exchange membranes
In recent years,metal-organic frameworks(MOFs)have attracted more and more attention as a new type of proton conductor in proton exchange membranes due to their large specific surface area and abundant pore structures.With the continuous deepening of research,to further improve the performance of MOFs composite proton exchange membrane,the physical morphology of MOFs materials in the proton exchange membrane has gradually developed from granular to continuous phase,and the composition of MOFs materials has also evolved from a single component to dual component.Based on the physical morphology of MOFs materials in proton exchange membranes,this paper divides them into MOFs crystal/polymer proton exchange membranes,the third phase reinforced MOFs/polymer composite proton exchange membranes,and MOFs nanofiber/polymer composite proton exchange membranes,comprehensively summarizes the research progress of MOFs materials in proton exchange membranes,and prospects the development direction of MOFs composite proton exchange membranes.