天津工业大学学报2024,Vol.43Issue(2) :10-15.DOI:10.3969/j.issn.1671-024x.2024.02.002

高密度聚乙烯三维网状纳微米纤维的强伸性能

Tensile properties of high-density polyethylene nano-micron fibers with three-dimensional network structure

西鹏 李永康 程博闻 夏磊 舒登坤
天津工业大学学报2024,Vol.43Issue(2) :10-15.DOI:10.3969/j.issn.1671-024x.2024.02.002

高密度聚乙烯三维网状纳微米纤维的强伸性能

Tensile properties of high-density polyethylene nano-micron fibers with three-dimensional network structure

西鹏 1李永康 1程博闻 2夏磊 1舒登坤2
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作者信息

  • 1. 天津工业大学材料科学与工程学院,天津 300387
  • 2. 天津科技大学轻工科学与工程学院,天津 300457
  • 折叠

摘要

为实现高密度聚乙烯三维网状纳微米纤维(PENFs)的自主化规模化生产,以高密度聚乙烯和二氯甲烷为原料,通过高压闪喷纺丝设备成功制备了性能优异的PENFs,采用响应面法对纺丝过程中各工艺参数进行优化,并对其力学性能和耐候性能进行分析.结果表明:PENFs的最佳制备工艺条件为纺丝温度176.3 ℃、纺丝压力8.6 MPa、纺丝溶液质量分数8.0%,此时制得的PENFs的断裂强度和断裂伸长率分别可达到29.1 cN/dtex和99.9%,优于芳纶和涤纶等常规纤维;定伸长和定载荷条件下,PENFs的弹性回复能力随着拉伸次数和载荷的增加而逐渐降低,拉伸伸长为5%时PENFs纤维的弹性回复率可达到92.8%且拉伸10次后降低至75.5%,拉伸载荷为1.2 N时PENFs纤维的弹性回复率为84.6%;放置在室外20 d内PENFs纤维的强伸性能损失较小,30 d后断裂强度和断裂伸长率明显降低,但纤维外貌并无明显变化.

Abstract

In order to achieve the large-scale production of high-density polyethylene nano-micron fibers with three-di-mensional network(PENFs),high-density polyethylene and dichloromethane were used as raw materials,PEN-Fs with high-performance were successfully prepared by high-pressure flash spinning equipment.The parame-ters during spinning process were optimized by response surface methodology.The mechanical and weather resis-tance properties of PENFs were analyzed.The results showed that the optimal preparation conditions for PENFs are spinning temperature of 176.3℃,spinning pressure of 8.6 MPa,and spinning solution mass fraction of 8.0%,then the fracture strength and elongation at break of the prepared PENFs can reach 29.1 cN/dtex and 99.9%,respectively,which are superior to conventional fibers such as aramid and polyester.Under constant e-longation and load conditions,the elastic recovery ability of PENFs decreases gradually with the increase of stretching times and load.When the stretching elongation is 5%,the elastic recovery rate of PENFs fibers can reach 92.8%,then decrease to 75.5%after stretching 10 times.When the stretching load is 1.2 N,the elastic recovery rate of PENFs fibers is 84.6%.The strength and elongation of PENFs fibers have little loss when PENFs fibers are placed outdoors for 20 d,and after 30 d the fracture strength and elongation at break of PENFs fibers significantly decrease,but there is no significant change in the appearance of the fibers.

关键词

高密度聚乙烯/纳微米纤维/三维网状结构/力学性能

Key words

high-density polyethylene/nano-micron fibers/three-dimensional network structure/mechanical properties

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基金项目

国家自然科学基金面上资助项目(51373118)

出版年

2024
天津工业大学学报
天津工业大学

天津工业大学学报

CSTPCD北大核心
影响因子:0.404
ISSN:1671-024X
参考文献量7
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