天津工业大学学报2024,Vol.43Issue(2) :22-28.DOI:10.3969/j.issn.1671-024x.2024.02.004

氯化胆碱改性聚酰胺纳滤膜的制备与分离性能

Preparation and separation properties of choline chloride modified polyamide nanofiltration membrane

陈英波 苏文轩
天津工业大学学报2024,Vol.43Issue(2) :22-28.DOI:10.3969/j.issn.1671-024x.2024.02.004

氯化胆碱改性聚酰胺纳滤膜的制备与分离性能

Preparation and separation properties of choline chloride modified polyamide nanofiltration membrane

陈英波 1苏文轩1
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作者信息

  • 1. 天津工业大学省部共建分离膜与膜过程国家重点实验室,天津 300387;天津工业大学材料科学与工程学院,天津 300387
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摘要

为了提高传统聚酰胺纳滤膜的分离性能,利用酰氯与羟基之间的酯化反应将带有正电荷的季铵盐氯化胆碱(CC)引入聚酰胺纳滤膜表面,制备在中性条件下具有近中性荷电性的氯化胆碱/聚酰胺纳滤膜,通过对无机盐的分离测试考察了 CC质量分数对薄膜复合(TFC)膜性能的影响.结果表明,当CC质量分数达0.10%时,改性效果最佳,TFC膜对Na2SO4、MgSO4和MgCl2均具有较高的截留率,具有改善的Mg2+/Li+分离能力,渗透通量提升了 315%.

Abstract

In order to improve the separation performance of traditional polyamide(PA)nanofiltration membrane,a posi-tively charged quaternary ammonium salt choline chloride(CC)was introduced into the surface of polyamide nanofiltration membrane by the esterification reaction between acyl chloride and hydroxyl,and a nearly neutral charge CC/PA nanofiltration membrane was prepared under neutral conditions.The influence of mass fraction of CC on the performance of thin film composite(TFC)membrane was investigated by the separation test of inor-ganic salts.The results showed that when the mass fraction of CC reached 0.1%,the modification effect was the best.The TFC membrane has a high retention on Na2SO4,MgSO4 and MgCl2,and the separation ability of Mg2+/Li+was improved.After modification,the permeation flux of TFC membrane was increased by 315%.

关键词

界面聚合(IP)/酯化反应/季铵盐/荷电/纳滤

Key words

interfacial polymerization(IP)/esterification reaction/quaternary ammonium salt/charging/nanofiltration

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基金项目

天津市重点研发计划科技支撑重点资助项目(20YFZCSN00930)

出版年

2024
天津工业大学学报
天津工业大学

天津工业大学学报

CSTPCD北大核心
影响因子:0.404
ISSN:1671-024X
参考文献量3
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