天津工业大学学报2024,Vol.43Issue(2) :68-74.DOI:10.3969/j.issn.1671-024x.2024.02.011

小麦淀粉生物基水凝胶合成及其辅助NO2--N的去除

Synthesis of wheat starch bio-based hydrogel and its assisted removal for NO2--N

许世超 祖彤彤 郝梦琛 杨杰
天津工业大学学报2024,Vol.43Issue(2) :68-74.DOI:10.3969/j.issn.1671-024x.2024.02.011

小麦淀粉生物基水凝胶合成及其辅助NO2--N的去除

Synthesis of wheat starch bio-based hydrogel and its assisted removal for NO2--N

许世超 1祖彤彤 2郝梦琛 2杨杰1
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作者信息

  • 1. 天津工业大学化学学院,天津 300387
  • 2. 天津工业大学环境科学与工程学院,天津 300387
  • 折叠

摘要

针对小麦淀粉(CS)凝胶力学性能较差的缺陷,利用小麦淀粉与聚乙烯醇(PVA)、硼砂(B)、海藻酸钠(SA)等天然/无机材料通过物理/化学交联合成了 PVA/B/CS和SA/B/CS 2种生物基水凝胶,考察其力学性能和溶胀性能;并制备生物基水凝胶包埋反硝化菌剂,考察其对水体中亚硝酸盐氮(NO2--N)的去除性能.结果表明:合成的2种生物基水凝胶均具有良好的力学性能,PVA/B/CS水凝胶的拉伸断裂伸长率最高可达1 088%,SA/B/CS水凝胶的拉伸断裂伸长率最高可达562%;PVA/B/CS27水凝胶包埋反硝化菌剂(D-PVA/B/CS2.7)去除水中NO2--N 30 h后,去除效率为94.81%;SA/B/CS2.7水凝胶包埋反硝化菌剂(D-SA/B/CS2.7)去除水中NO2--N 40 h后,去除效率为94.99%,说明所合成的生物基水凝胶具有辅助去除水体中氨氮的效果.

Abstract

Aiming at the defect of poor mechanical properties of wheat starch(CS)gel,PVA/B/CS and SA/B/CS bio-based hydrogels were synthesized by physical/chemical crosslinking of wheat starch with natural/inorganic materials such as polyvinyl alcohol(PVA),borax(B)and sodium alginate(SA).The mechanical properties and swelling properties of two composite bio-based hydrogels were studied.Bio-based hydrogel entrapped denitrifying bacte-ria was prepared,and its removal performance of nitrite nitrogen(NO2-N)in water was investigated.The results showed that the two bio-based hydrogels had good mechanical properties,the tensile elongation at break of PVA/B/CS hydrogels was up to 1 088%,and the tensile elongation at break of SA/B/CS hydrogels was up to 562%.The removal efficiency of PVA/B/CS2.7 hydrogel-embedded denitrifying bacteria(D-PVA/B/CS2.7)for NO2--N in water was 94.81%after 30 h.The removal efficiency of SA/B/CS2.7 hydrogel-embedded denitrifying bacteria(D-SA/B/CS2.7)for NO2--N in water was 94.99%after 40 h.It indicates that the synthesized bio-based hydrogel has an auxiliary effect on the removal of ammonia nitrogen in water.

关键词

小麦淀粉/生物基水凝胶/固定载体/生物脱氮/力学性能

Key words

wheat starch/bio-based hydrogel/fixed carrier/biological denitrification/mechanical property

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基金项目

国家自然科学基金资助项目(51772208)

国家自然科学基金资助项目(51678409)

出版年

2024
天津工业大学学报
天津工业大学

天津工业大学学报

CSTPCD北大核心
影响因子:0.404
ISSN:1671-024X
参考文献量8
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