首页|应用于太阳能储热的膨胀石墨/石蜡复合相变材料的制备与热性能

应用于太阳能储热的膨胀石墨/石蜡复合相变材料的制备与热性能

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为了改善太阳能储热用相变材料的性能,以石蜡为基材,通过添加分散剂和不同质量分数的膨胀石墨,制备出具有良好热性能的复合相变材料。实验测试复合相变材料在熔化和凝固过程的温度变化,分析复合相变材料的蓄放热特性,并采用参比温度法得出复合相变材料的主要热物性参数。数值模拟复合相变材料的熔化过程,比较分析温度的模拟值与实验数据,研究复合相变材料的固液相变化规律和微观流场。结果表明:添加膨胀石墨可增强相变材料的传热,提高相变材料的蓄、放热性能,添加1。5%膨胀石墨的相变材料的热传导率是纯相变材料的1。49倍;随着膨胀石墨的添加量增加,复合相变材料黏度增大,使对流换热强度减弱,同时复合相变材料的潜热也逐渐降低,使蓄热量减小;膨胀石墨添加量(质量分数)为1。0%的复合相变材料蓄放热性能最佳,放热时间比纯相变材料缩短38。06%;膨胀石墨的添加量越高,复合相变材料的熔化速率越快;膨胀石墨添加量为1%的复合相变材料蓄放热性能最佳。
Preparation and thermal performance of expanded graphite/paraffin composite phase change materials for solar thermal storage
In order to improve the performance of phase change material(PCM)for solar thermal storage,composite PCMs with good thermal performance were prepared using paraffin by adding dispersants and different mass fractions of expanded graphite(EG).The temperature changes were tested experimentally during melting and solidification,in order to analyze the heat storage and release characteristics of composite PCMs.And the main thermophysical parameters were obtained using the T-History method.Numerical simulation was carried out to study the solid-liquid phase change and flow field of composite PCMs during melting process,and the numerical temperature were compared with experimental data.The results show that the heat transfer,heat storage,and release perfor-mance of PCM are enhanced by adding EG.The thermal conductivity of PCM with 1.5%EG is 1.49 times that of pure PCM.As the EG additive amount increases,the viscosity of composite PCM increases,which weakens the convective heat transfer intensity.And the latent heat of composite PCM also decreases,which decreases the heat storage capacity.The composite PCM with 1%EG addition has the best heat storage and release performance,and its heat release time is shortened by 38.06%compared that of to pure PCM.The higher the amount of EG added,the faster the melting rate of composite PCM.The composite PCM with 1%EG addition has the best heat storage and release performance.

solar thermal storagecomposite phase change materialsthermal conductivityphase change latent heatnu-merical simulation

许立宪、张勇、梁诺、张旭

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甘肃省建设设计咨询集团有限公司,兰州 730050

天津工业大学航空航天学院,天津 300387

太阳能储热 复合相变材料 热导率 相变潜热 数值模拟

天津市科技计划项目甘肃省住房和城乡建设厅科技计划项目

18JCTPJC60200JT2022-48

2024

天津工业大学学报
天津工业大学

天津工业大学学报

CSTPCD北大核心
影响因子:0.404
ISSN:1671-024X
年,卷(期):2024.43(4)