天津化工2024,Vol.38Issue(1) :50-53.DOI:10.3969/j.issn.1008-1267.2024.01.016

四氧化三钴/膨润土活化过一硫酸盐降解盐酸洛美沙星

Degradation of lomefloxacin hydrochloride through the activated peroxymonosulfate by bentonite-supported Co3O4

唐雅琳 徐丁一 陆宣郦 黄愉 朱友莲 魏光涛
天津化工2024,Vol.38Issue(1) :50-53.DOI:10.3969/j.issn.1008-1267.2024.01.016

四氧化三钴/膨润土活化过一硫酸盐降解盐酸洛美沙星

Degradation of lomefloxacin hydrochloride through the activated peroxymonosulfate by bentonite-supported Co3O4

唐雅琳 1徐丁一 1陆宣郦 1黄愉 1朱友莲 1魏光涛1
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作者信息

  • 1. 广西大学化学化工学院,广西南宁 530004
  • 折叠

摘要

本文以合成的四氧化三钴/膨润土(Co3O4/Bent)活化过一硫酸盐(PMS)降解盐酸洛美沙星(LOMH),探究了反应温度、LOMH质量浓度和腐殖酸质量浓度对LOMH降解的影响,并研究了该催化剂对不同质量浓度的盐酸四环素(TC-HCL)、左氧氟沙星(LVFX)、环丙沙星(CIP)的降解效果.实验结果表明,在反应温度为40℃、LOMH初始质量浓度为10 mg/L时,Co3O4/Bent降解LOMH的效果最佳,60 min时LOMH的降解率为 97.6%;腐殖酸对LOMH的降解具有轻微的抑制作用;Co3O4/Bent催化活化PMS对TC-HCL、LVFX、CIP皆具有良好的降解效果.

Abstract

In this experiment,bentonite-supported Co3O4(Co3O4/Bent)was prepared and used to activate the peroxymonosulfate(PMS)for degradation of lomefloxacin hydrochloride(LOMH).The effects of reaction temperature,LOMH concentration and humic acid concentration on the degradation of LOMH were investigated.In addition,the degradation effects of the catalyst on tetracycline hydrochloride(TC-HCL),levofloxacin(LVFX)and ciprofloxacin(CIP)at different concentrations were also studied.The experimental results showed that when the reaction temperature was 40℃ and the concentration of LOMH was 10 mg/L,Co3O4/Bent showed the best degradation effect of LOMH,and the degradation ratio of LOMH at 60 min was 97.6%.Humic acid slightly inhibited the degradation of LOMH.Co3O4/Bent has a good degradation effect on TC-HCL,LVFX and CIP.

关键词

四氧化三钴/膨润土/盐酸洛美沙星/过一硫酸盐

Key words

cobaltosic oxide/bentonite/lomefloxacin hydrochloride/peroxomonosulfate

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基金项目

广西自然科学基金(2021GXNSFAA075006)

大学生创新创业训练计划项目(S202210593428)

出版年

2024
天津化工
天津市化工科技信息研究所

天津化工

影响因子:0.214
ISSN:1008-1267
参考文献量8
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