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氮缺陷g-C3N4光降解罗丹明B

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本文通过简单的一步煅烧法制备了氮缺陷g-C3N4 光催化剂材料,并通过X射线粉末衍射(XRD)、傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)以及紫外可见漫反射吸收光谱(UV-vis)对所制备的光催化剂的结晶度、形貌、特征官能团和光学特性方面进行了表征分析.与此同时,通过光降解罗丹明B的实验探究了所制备的光催化剂的光催化性能.实验结果表明,当罗丹明B的质量浓度为10 mg/L,催化剂的用量为20 mg时,氮缺陷g-C3N4 具有优异的光降解性能,在20 min内对罗丹明B的光降解效率达到了 100%.这表明缺陷的引入可以有效提高原始g-C3N4 的光吸收范围,促进光生电子与空穴对的分离,增强其光催化效率.本研究为有机污染物的处理提供了一定的理论指导价值,具有一定的实际应用前景.
Nitrogen-deficient g-C3N4 photodegradation of rhodamine B
The g-C3N4 photocatalyst materials with nitrogen defects were prepared by a simple one-step calcination method,and the crystallinity,morphology,characteristic functional groups and optical properties of the prepared photocatalysts were characterized by X-ray powder diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),Scanning electron microscopy(SEM)and Ultraviolet-visible diffuse reflectance absorption spectroscopy(UV-vis).The photocatalytic properties of the prepared photocatalysts were also investigated by photodegradation of Rhodamine B.The corresponding experimental results show that ND-g-C3N4 has excellent photodegradation performance when the concentration of rhodamine B is 10 mg/L and the amount of catalyst is 20 mg,and the photodegradation efficiency of Rhodamine B reaches 100%within 20 min.This indicates that the introduction of defects will effectively improve the light absorption range of pristine g-C3N4,promote the separation of photogenerated electron and hole pairs,and enhance photocatalytic efficiency.This study provides some theoretical guidance value for the treatment of organic pollutants and some practical application prospects.

nitrogen defectsgraphite carbon nitridephotodegradationrhodamine B

陈启旭

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南华大学,衡阳 421001

氮缺陷 石墨氮化碳 光降解 罗丹明B

2024

天津化工
天津市化工科技信息研究所

天津化工

影响因子:0.214
ISSN:1008-1267
年,卷(期):2024.38(2)
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