首页|高性能FeCl2·4H2O/聚硫酸酯(PSE)中空纤维共混超滤膜性能和结构的探究

高性能FeCl2·4H2O/聚硫酸酯(PSE)中空纤维共混超滤膜性能和结构的探究

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以四水氯化亚铁(FeCl2·4H2O)为改性剂,采用非溶剂致相分离法(NIPS)制备FeCl2·4H2O/聚硫酸酯(PSE)中空纤维共混超滤膜,本文研究了FeCl2·4H2O的质量分数对FeCl2·4H2O/PSE中空纤维共混超滤膜微观结构、截留性能和力学性能等影响.实验采用场发射扫描电子显微镜(SEM)观察超滤膜的形貌结构,使用接触角测量仪和电子拉力试验机测试超滤膜的亲水性和力学性能,利用实验室自制的测试装置测试纯水通量和截留率.实验结果表明:当Fe-Cl2·4H2O为 5%时,FeCl2·4H2O/PSE中空纤维共混超滤膜的性能最优,其纯水通量为 210 L/(m2·h).
Investigation of the performance and structure of high-performance FeCl2·4H2O/polysulfate(PSE)ultrafiltration membranes
Preparation of FeCl2·4H2O/PSE hollow fiber blended ultrafiltration membrane by non-solvent-induced phase separation(NIPS)method using FeCl2·4H2O as modifier.The effects of FeCl2·4H2O content on the microstructure,retention performance and mechanical properties of FeCl2·4H2O/PSE hollow fiber blended ultrafiltration membranes were investigated.The morphology of the membranes was observed using a scanning electron microscope(SEM).The hydrophilicity and mechanical properties of the membranes were observed using a contact angle measurement instrument and an electronic tensile testing machine,respectively.The pure water flux and rejection rate were measured using a self-made measuring device.The experimental results showed that the membrane exhibited optimal performance when the FeCl2·4H2O content was 5%.The pure water flux of the membrane was 210 L/(m2·h).

polysulfateFeCl2·4H2Ohollow fiber ultrafiltration membrane

马凌飞、王薇、王佳琦、李玮阳

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天津工业大学材料科学与工程学院,天津 300387

聚硫酸酯 四水氯化亚铁 中空纤维共混超滤膜

中央引导地方项目院士类自治区项目

ZYYD2023B182022LQ02002

2024

天津化工
天津市化工科技信息研究所

天津化工

影响因子:0.214
ISSN:1008-1267
年,卷(期):2024.38(5)