首页|花生壳生物炭的制备及其对水中罗丹明B的吸附性能研究

花生壳生物炭的制备及其对水中罗丹明B的吸附性能研究

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以花生壳为原料,KOH为改性剂,通过限氧热解法在 200℃下制备花生壳生物炭用于吸附水中的罗丹明B.采用单因素试验,考察了罗丹明B初始浓度、溶液pH、吸附时间、生物炭投加量等对罗丹明B吸附效果的影响,并对吸附机制进行了分析.研究表明,在活性炭投加量为20 mg,罗丹明B溶液体积 25.00 mL、初始质量浓度 1.00 mg/L,转速 150 r/min的条件下吸附 75 min,此时去除率达 97.90%.参数拟合结果表明,准二级动力学方程(R2=0.9982)能够更好地描述改性花生壳生物炭对罗丹明B的吸附过程,吸附等温线更遵循Langmuir等温吸附模型,属于单分子层化学吸附.
Preparation of peanut shell biochar and its adsorption performance on Rhodamine B in water
Using peanut shell as raw material and KOH as modifier,peanut shell biochar was prepared for adsorption of Rhodamine B in water by oxygen-limited pyrolysis at 200℃.The effects of initial concentration of Rhodamine B,pH of solution,adsorption time and dosage of biochar on the adsorption of Rhodamine B were investigated by single factor experiment,and the adsorption mechanism was also analyzed.The results showed that at the dosage of 20 mg,the volume of 25.00 mL,the initial concentration of 1.00 mg/L,the rotate speed of 150 r/min and the adsorption time of 75 min,the removal rate reached 97.90%.The results of parameter fitting showed that the adsorption process of Rhodamine B by modified peanut shell biochar followed the quasi-second-order kinetic equation(R2=0.9982),and the adsorption isotherm followed the Langmuir isotherm adsorption model,which belonged to single molecular layer chemisorption.

peanut shellbiocharRhodamine BadsorptionKOH

陆星蓉、蒋星宇、胡欣、邱钰桁、卜路霞、宋振兴

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天津农学院 基础科学学院,天津 300392

天津朗缪新材料科技有限公司,天津 300384

花生壳 生物炭 罗丹明B 吸附 KOH

天津市大学生创新创业训练计划项目天津市大学生创新创业训练计划项目枣庄市自主创新及成果转化计划天津市教委科研计划项目天津市科技计划项目

2022100610502023100611192022GH202021KJ11320YDTPJC01080

2024

天津农学院学报
天津农学院

天津农学院学报

影响因子:0.612
ISSN:1008-5394
年,卷(期):2024.31(4)
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