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烟丝掺配输送及卷制过程中的热解特性变化分析

Pyrolysis Characteristics Analysis of Cut Tobacco during the Blending,Transportation and Cigarette Making processes

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为研究烟丝在掺配输送及卷制过程中的热解特性变化规律,利用热重分析技术和热分析动力学方法跟踪分析了不同加工环节烟丝的热失重特征参数变化和差异.结果表明:(1)不同加工环节烟丝整体热解失重规律一致,均包含脱水干燥、挥发性成分损失、半纤维素和纤维素分解、木质素分解与炭化、无机盐分解等阶段,各样品不同热失重阶段的温度区间一致,但阶段失重率有差异;(2)JXQ、JXH和CPS样品在无机盐分解阶段的失重率接近,并明显高于其他样品,不同烟丝样品的综合热解指数CPI范围为4.10×10-5%.(min ×℃2)-1~4.65×10-5%·(min ×℃2)-1,BZS样品的CPI最低,CPI随着加工环节的进行呈现逐渐降低的趋势;(3)样品在脱水干燥和纤维素分解阶段的热分解过程均符合F1.5级化学反应模型,但不同样品的热解动力学参数存在一定差异.本研究揭示了烟丝在热解过程中的化学反应动力学参数存在一定的差异,在加工过程中烟丝的配方成分可能存在一定程度的波动.
To investigate the evolving pyrolysis characteristics of tobacco during blending,conveying,and rolling,we tracked and analysed changes in the heat loss characteristic parameters at different processing stages using thermogravimetric analysis technology and thermal analysis kinetic method.The results indicated that:(1)pyrolytic weight loss of tobacco remained consistent throughout various processing stages,including dehydration,drying,loss of volatile components,hemicellulose and cellulose decomposition,lignin decomposition and charring,and inorganic salt decomposition.The temperature intervals between the different heat loss stages of the samples were consistent,but the rate of weight loss varied.(2)During the inorganic salt decomposition stage,JXQ,JXH,and CPS samples exhibited weight loss rates that were significantly higher than those of the other samples.The composite pyrolysis indices(CPIs)of the different tobacco samples ranged from 4.10×10-5%·(min ×℃2)-1 to 4.65×10-5%·(min ×℃2)-1,with the BZS sample having the lowest CPI.The CPIs showed a decreasing trend with each processing session.(3)The thermal decomposition processes of the samples during dehydration,drying,and cellulose decomposition followed the F1.5-level chemical reaction model.However,the pyrolysis kinetic parameters varied among the different samples.It has been revealed that there are differences in the kinetic parame-ters of chemical reactions during pyrolysis.Additionally,there may be fluctuations in the formulation composition of tobacco during processing.

cut tobaccouniformityblendingpyrolysis characteristicsdegree of difference

王姗姗、刘畅、孙皓月、孟许宽、张佳儒、李俊

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湖北中烟工业有限责任公司,湖北武汉 430040

烟丝 均匀性 掺配 热解特性 差异度

湖北中烟工业有限责任公司青年托举项目郑州轻工业大学星空众创空间项目

2021ZCKJ301

2024

天津农业科学
天津农业科学院信息研究所

天津农业科学

影响因子:0.705
ISSN:1006-6500
年,卷(期):2024.30(2)
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