天津师范大学学报(自然科学版)2024,Vol.44Issue(1) :49-55.DOI:10.19638/j.issn1671-1114.20240107

Ni-MOF/NF自支撑电极的制备及电化学性能

Preparation and electrochemical properties of self-supported Ni-MOF/NF electrodes

白晨晨 李炳君 郑子朝 于跃 韩燕
天津师范大学学报(自然科学版)2024,Vol.44Issue(1) :49-55.DOI:10.19638/j.issn1671-1114.20240107

Ni-MOF/NF自支撑电极的制备及电化学性能

Preparation and electrochemical properties of self-supported Ni-MOF/NF electrodes

白晨晨 1李炳君 1郑子朝 1于跃 1韩燕1
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作者信息

  • 1. 天津师范大学 物理与材料科学学院,天津 300387
  • 折叠

摘要

为改善金属有机骨架材料(MOFs)的导电性和电容性能,采用阴极还原电沉积方法,在泡沫镍(NF)基底表面原位生长镍基金属有机框架(Ni-MOF)用于制备自支撑Ni-MOF/NF复合电极,并采用SEM、XRD和FT-IR等手段对其形貌和结构进行表征.实验结果表明:Ni-MOF为棒状晶体自组装成的花状结构,随机分布在NF表面.当反应时间为 1 200s时,Ni-MOF花状结构覆盖整个NF表面.电化学测试表明,沉积 900 s所得Ni-MOF/NF(900)电极具有较好的电容性能,当电流密度为 1 mA/cm2 时,其比电容可达 5 415 mF/cm2,在超级电容器方面具有潜在的应用前景.

Abstract

To improve the conductivity and capacitive performance of metal-organic frameworks(MOFs),nickel-based metal-organic frameworks(Ni-MOF)have been in-situ grown on the surface of nickel foam(NF)substrate by cathodic electrodeposi-tion to construct self-supported Ni-MOF/NF composite electrodes.The morphology and structure of composite electrodes are characterized by SEM,XRD and FT-IR.The test results show that Ni-MOF has a flower-like structure composed of rod-like crys-tals,which is randomly distributed on the NF surface.When the deposition time is 1200 s,the Ni-MOF flowers cover the entire NF surface.The Ni-MOF/NF electrode obtained at the deposition time of 900 s has better electrochemical performances with a high specific capacitance of 5415 mF/cm2 at 1 mA/cm2,indicating its potential application in supercapacitors.

关键词

Ni-MOF/阴极还原电沉积/自支撑电极/电化学性能/超级电容器

Key words

Ni-MOF/cathodic electrodeposition/self-supported electrodes/electrochemical performance/supercapacitors

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基金项目

国家自然科学基金(22379113)

天津市企业科技特派员项目(22YDTPJC00780)

天津市研究生科研创新项目(2022SKYZ198)

出版年

2024
天津师范大学学报(自然科学版)
天津师范大学

天津师范大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.311
ISSN:1671-1114
参考文献量27
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