首页|磺酸型水性聚氨酯的合成与性能研究

磺酸型水性聚氨酯的合成与性能研究

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以甲苯二异氰酸酯(TDI-80)和聚醚二元醇(N210)为主要原料,1,4-丁二醇(BDO)为小分子扩链剂,乙二胺基磺酸钠(A95)为亲水扩链剂,成功制备了磺酸型水性聚氨酯.研究了A95含量对水性聚氨酯乳液及胶膜性能的影响.通过红外(FT-IR)、透射电镜(TEM)、热重分析(TGA)、粒径和力学性能测试等分析手段研究了乳液及其涂膜的结构与性能.结果表明:所制备的水性聚氨酯乳液粒子规整性较好,分散均匀;随着A95含量增加,粒径逐渐减小;当A95含量为5%时,乳液具有良好的室温贮存稳定性,胶膜的综合性能优异.
Study on Synthesis and Performance of Sulfonated Waterborne Polyurethane
With the toluene diisocynate(TDI) and polyether glycol(N210; as the main materials,1,4 -butanediol(BDO) as small molecular chain extender, ethylenediamine sodium sulphonate( A95 ) as hydro-philic chain - extender, the title sulfonated waterborne polyurethane was prepared. The influence of A95 content on the performance of emulsion and film was studied. The properties and structure of the latex and its film was investigated by FT - IR, TEM, TGA, particle size, mechanical property and so on. The results showed that the tacticity and dispersivity of sulfonated waterborne polyurethane were satisfied. As A95 con-tent increased, the particle size of emulsion was decreased; when the content of A95 was 5% , emulsion showed good room temperature storage stability and the excellent film comprehensive performance.

hydrophilic chain -extendersulfonated waterborne polyurethanetoluene diisocynatepolyether glycol

徐绍娟、王平华、刘春华、陈伟

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合肥工业大学化工学院高分子材料科学与工程系,合肥230009

亲水扩链剂 磺酸型水性聚氨酯 甲苯二异氰酸酯 聚醚二元醇

2013

涂料工业
中海油常州涂料化工研究院中国化工学会涂料涂装专业委员会

涂料工业

CSTPCDCSCD北大核心
影响因子:0.66
ISSN:0253-4312
年,卷(期):2013.43(1)
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