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磺化石墨烯在丙烯酸酯涂料中的性能研究

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在纯丙乳液中加入质量分数为0.1%~2.0%的磺化石墨烯(S-GNS),制备了磺化石墨烯/丙烯酸酯涂料,并对S-GNS的结构进行了分析,测定了漆膜的基本性能、力学性能、耐水性、导电性、导热性、气体阻隔性.结果表明:S-GNS用量为0.1%时,漆膜的力学性能、耐水性与导电性得到明显改善,拉伸强度和断裂伸长率较空白样分别提高了38.8%和42.8%,水接触角从69.5°提高到90.5°,漆膜达到了导电渗流临界值,表面电阻率下降了93.8%.用量为1.0%时,S-GNS对涂料导热性能提升较为明显,漆膜的导热率提升了58.9%.漆膜的透气系数随着S-GNS用量的增加逐渐减小,用量为2.0%时,漆膜的透气系数降低了97.1%.
Study on Performance of Acrylate Coatings Filled with Sulfonated Graphene
Sulfonated graphene/acrylate coatings were prepared by adding 0.1wt%~ 2.0wt% sulfonated graphene into acrylic emulsion.The structure of S-GNS and the performance including mechanical,electrical,thermal conductivity and gas barrier of the film were tested and analyzed.It was found that there were many active functional groups on the surface of S-GNS which could improve the performance of coatings.The results indicated that mechanical properties and of electrical conductivity of coating film were notably improved.When the amount of sulfonated graphene was loaded 0.1wt%,the tensile strength and elongation at break of the film were improved by 38.8% and 42.8% respectively as compared with the control samples.The electrical conductivity reached percolation threshold and the surface resistivity was decreased by 93.8%.The thermal conductivity of the film comprising 1.0wt% sulfonated graphene was increased by 58.9%.Coefficient of permeability of the film gradually decreased with the increase of sulfonated graphene loading,and was decreased by 97.1% when the addition of sulfonated graphene was 2.0wt%.

acrylate coatingsulfonated graphenemechanical propertyelectrical conductivitybarrier property

吴平、叶昕瑜、舒杨、王继虎、温绍国

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上海工程技术大学化学化工学院,上海201620

丙烯酸酯涂料 磺化石墨烯 力学性能 导电性 阻隔性

上海工程技术大学大学生创新项目校企合作项目[

cs160400915HG-001

2017

涂料工业
中海油常州涂料化工研究院中国化工学会涂料涂装专业委员会

涂料工业

CSTPCDCSCD北大核心
影响因子:0.66
ISSN:0253-4312
年,卷(期):2017.47(3)
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