首页|糠醛类衍生物在水除锈工艺中的防锈性能及应用研究

糠醛类衍生物在水除锈工艺中的防锈性能及应用研究

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以生物质材料糠醛衍生物为主体,采用葡萄糖酸钠、苯甲酸钠复配制得生物基防锈剂.通过静态失重、接触角、扫描电镜、防锈性能测试以及涂层附着力和耐盐雾性等测试方法对其防锈性能,以及与EP-01环氧富锌底漆和MC-WEP-3水性环氧富锌底漆的配套使用性能进行了研究.研究结果表明,HMF在90 ℃条件下,其缓蚀性能基本丧失;30℃条件下,在1 mol/L HC1溶液中,300 ppm HMF对Q235的缓蚀率达到69.4%;添加2%防锈剂的样板在水除锈工艺后24 h内表面无明显返锈,且对后续溶剂型和水性环氧富锌底漆的附着力、耐盐雾性无明显影响.
Study on Rust Prevention Performance and Application of Bio-Based Furfural Derivatives in Water Rust-Removing Process
A bio-based rust inhibitor is prepared by using biomass material furfural derivatives as the matrix substance in addition to compounding of sodium gluconate and sodium benzoate,.The rust resistance of the bio-based rust inhibitor is investigated via a series of tests including static weight loss,contact angle,scanning electron microscopy,rust resistance testing,coating adhesion and salt spray resistance,etc.And its compatibility with EP-01 epoxy zinc rich primer and MC-WEP-3 waterborne epoxy zinc rich primer is also studied.The results indicate that the corrosion inhibition performance of HMF is basically lost at 90 ℃.the corrosion inhibition rate of 300 ppm HMF on Q235 at 30 ℃ in a lmol/L HCl solution can reach up to 69.4%.The addition of 2%rust inhibitor in water rust-removing process enables no obvious rust on the surface of the sample within 24 hours,and has no impact on the adhesion and salt spray resistance of subsequent solvent-based or waterborne epoxy zinc rich primers.

furfural derivativewater rust-removingcorrosion inhibitoranticorrosive coating

林世明、邹美初、赵起锋、徐慧

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中海油常州涂料化工研究院有限公司,江苏常州 213016

糠醛衍生物 除锈 腐蚀 防锈剂 防腐涂层

2024

涂层与防护
中海油常州涂料化工研究院,中国化工学会涂料涂装专业委员

涂层与防护

影响因子:0.452
ISSN:1672-2418
年,卷(期):2024.45(1)
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