首页|正交试验法研究模拟土壤溶液中SO42-、Cl-和CO32-对低碳钢腐蚀的影响

正交试验法研究模拟土壤溶液中SO42-、Cl-和CO32-对低碳钢腐蚀的影响

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为了研究中性土壤中SO42-、Cl-和CO32-3种离子对低碳钢腐蚀的影响,以中性土壤中3种阴离子的含量为基础,将3种离子作为实验因素,3种离子浓度作为水平,设计了正交试验.采用全浸实验,1 a后通过观测低碳钢的表面腐蚀形貌、分析腐蚀产物成分,并对腐蚀速率和点蚀深度进行极差分析.发现模拟土壤溶液中CO32-含量低时,低碳钢表面的腐蚀产物主要是Fe3O4、α-FeOOH和γ-FeOOH,锈层松散易清除,低碳钢以整体腐蚀为主;CO32-含量增高,低碳钢表面的腐蚀产物主要是Fe3O4 和α-FeOOH,锈层致密不易清除,低碳钢发生点蚀.在中性土壤模拟溶液中3种阴离子对低碳钢腐蚀失重速率的影响排序为:SO42->Cl->CO32-,对低碳钢点蚀深度的影响排序为:CO32->SO42->Cl-.中性土壤中,SO42-对低碳钢的整体腐蚀影响最大,CO32-对点蚀的影响最大.
Effects of SO42-,Cl- and CO32- on Corrosion of Mild Steel in Simulated Soil Solution Studied by Orthogonal Test
To study the effects of SO42-,Cl-and CO32-ions on the corrosion of mild steel in neutral soil,the three ions are taken as experimental factors and orthogonal test method is adopted.After 1 year of total immersion experiment,through observing the corrosion morphology,analyzing the composition of corrosion products and range analysis,it is found that the corrosion products on the surface of low carbon steel are mainly Fe3O4,α-FeOOH and γ-FeOOH when the content of CO32-in simulated soil solution is low,and the rust layer is loose and easy to remove.The overall corrosion occurs mainly on surface of mild steel.When the content of CO32-is increased,the corrosion products on the surface of mild steel are mainly Fe3O4 and α-FeOOH,and the rust layer is dense and hard to remove,wherein the pitting corrosion occurs.The effect of the three anions in soil solution on the corrosion loss rate of mild steel is ranked as SO42->Cl->CO32-,and the effect on the pitting depth of low carbon steel is ranked as CO32->SO42-->Cl-.

orthogonal test methodmild steelsimulation soil solutionanionic and corrosionrange analysis

李莎莎、曹雪雅、赵华宇、卢彩彬、芦玉峰

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西北核技术研究所,西安 710600

正交试验法 低碳钢 模拟土壤溶液 阴离子 腐蚀 极差分析

2024

涂层与防护
中海油常州涂料化工研究院,中国化工学会涂料涂装专业委员

涂层与防护

影响因子:0.452
ISSN:1672-2418
年,卷(期):2024.45(3)
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