涂层与防护2024,Vol.45Issue(7) :1-11.DOI:10.3969/j.issn.2096-8639.2024.07.001

光伏玻璃用高透明无氟超疏水涂层的制备及其性能研究

Research on Preparation and Performance of High Transparency,Non-fluorinated Superhydrophobic Coating for Photovoltaic Glass

徐荣康 叶红 吴明元 吴庆云 杨建军 刘久逸 张建安
涂层与防护2024,Vol.45Issue(7) :1-11.DOI:10.3969/j.issn.2096-8639.2024.07.001

光伏玻璃用高透明无氟超疏水涂层的制备及其性能研究

Research on Preparation and Performance of High Transparency,Non-fluorinated Superhydrophobic Coating for Photovoltaic Glass

徐荣康 1叶红 1吴明元 2吴庆云 2杨建军 2刘久逸 2张建安3
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作者信息

  • 1. 安徽大学化学化工学院,合肥 230601
  • 2. 安徽大学化学化工学院,合肥 230601;安徽省绿色高分子材料重点实验室,合肥 230601
  • 3. 安徽大学化学化工学院,合肥 230601;安徽省绿色高分子材料重点实验室,合肥 230601;安徽大学物质科学与信息技术研究院,合肥 230601
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摘要

在光伏玻璃上制备透明超疏水涂层的方法有多种,但大多数纳米粒子采用氟硅烷改性,不仅对环境不友好,而且对人体有害.在本研究中,提出了一种喷涂不含氟的纳米粒子来制备透明超疏水涂层.经过十八胺(ODA)修饰的SiO2纳米颗粒附着在半固化的粗糙水性聚氨酯(WPU)层上,提供低表面能和粗糙度.采用非氟改性剂六甲基二硅氮烷(HMDS),进一步提高了涂层的疏水性能.实验结果表明,在400~700 nm波长范围内,EW3涂层的平均透过率为90.63%,平均静态水接触角(WCA)为155.8°.在自清洁试验中,EW3涂层表面没有砂石残留.一系列的耐久性测试表明,EW3涂层具有优异的粘接性、耐腐蚀性、抗辐射性以及抗水流冲击能力.这种环保和低成本的制备方法为光伏玻璃和其他领域制备环境友好型透明超疏水涂层提供了新的思路.

Abstract

Nowadays,there are several ways to prepare transparent superhydrophobic films on the surface of photovoltaic glass covers,but the nanoparticles in coating system are mostly modified by fluorosilane,which might threaten environment and human health.In this research,a method of preparing transparent superhydrophobic coating by spraying non-fluorinated nanoparticles is proposed.SiO2 nanoparticles modified with octadecylamine(ODA)are adhered on the semi-cured waterborne polyurethane(WPU)layer to provide low surface energy and roughness.The non-fluorinated modifier hexamethyldisilazane(HMDS)is used to further enhance the hydrophobic performance of the coating.Experimental results show that within the wavelength range of 400 to 700 nm,the average transmittance of the EW3 coating is 90.63%,and its average static water contact angle(WCA)is 155.8°.The self-cleaning test result shows that there is no dust residue on the surface of the EW3 coating.The durability test result indicates that the EW3 coating exhibits excellent adhesion,corrosion resistance,radiation resistance and resistance to water flow impact.This environmental friendly and cost-effective preparation method provides a new approach for the preparation of environmental friendly transparent superhydrophobic coatings on photovoltaic glass and other fields.

关键词

超疏水涂层/二氧化硅纳米粒子/透明/无氟

Key words

superhydrophobic coating/silica nanoparticles/transparent/non-fluorinated

引用本文复制引用

基金项目

安徽省高等学校自然科学研究重大项目(KJ2019ZD01)

安徽省留学人员创新重点项目(2019LCX006)

安徽省高等学校自然科学研究项目(KJ2018A0036)

出版年

2024
涂层与防护
中海油常州涂料化工研究院,中国化工学会涂料涂装专业委员

涂层与防护

影响因子:0.452
ISSN:1672-2418
参考文献量2
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