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锰系磷化工艺参数对零部件结晶尺寸和覆盖率的影响分析

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采用扫描电子显微镜(SEM)研究了在零部件处理的锰系磷化工艺中,通过改变表面调整剂质量浓度和磷化的温度、酸比、Fe2+质量浓度以及Ni2+质量浓度这些影响因素,观察零部件表面结晶覆盖率和晶体结构尺寸.实验结果表明,随着表面调整剂的质量浓度增加,结晶尺寸逐渐变小;随着处理温度的升高,结晶由不完整到尺寸粗大的转变;随着酸比的增加,晶核形成困难到均一再到磷化膜变薄;Fe2+和Ni2+的引入对晶体尺寸也有一定的影响,为锰系磷化处理工艺参数管控提供参考.
Influence of Manganese Based Phosphating Process Parameters on Crystal Size and Coverage Rate of Components
The scanning electron microscope(SEM)was used to study the effect of surface modifier concentration,phosphating temperature,acid ratio,Fe2+concentration and Ni2+concentration on the surface crystal coverage and crystal structure size of the manganese based phosphating process in component processing.The experimental results indicate that the increase of the surface modifier concentration is resulted in decrease of the crystal size.The increase of the processing temperature can enable the crystallization to transform from incomplete to coarse in size.The increase of acid ratio is helpful for the formation of crystal nucleus from nuiform to thinner phosphating film.The introduction of Fe2+and Ni2+also has a certain impact on the crystal size,providing reference for the control of process parameters in manganese based phosphating treatment.

componentsmanganese based phosphatingcrystal sizecoverage rate

王连、彭杨、周宪民、周瑜

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沈阳帕卡濑精有限总公司,沈阳 110000

零部件 锰系磷化 结晶尺寸 覆盖率

2024

涂层与防护
中海油常州涂料化工研究院,中国化工学会涂料涂装专业委员

涂层与防护

影响因子:0.452
ISSN:1672-2418
年,卷(期):2024.45(11)