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石蜡/枣碳复合相变材料的制备及性能研究

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本研究以废弃红枣的冻干红枣粉(FDJ)作为相变材料载体,采用真空浸渍法从相变芯材料中吸附石蜡,研究材料的储热能力和热响应效率,并采用聚乙烯醇(PVA)水溶液降低材料的泄漏值.结果表明,聚乙烯醇/冻干枣粉石蜡复合相变材料(PVA/CFDJ)的相变焓达到126.41 J/g,导热系数增加到0.216 3 W/m·K,较纯石蜡导热系数提高了60.5%.在储放热循环测试中,循环100次,PVA/CFDJ材料的焓值仅仅减少了4%左右,泄漏率降低至 3.2%.PVA/CFDJ复合材料在具有较高地相变焓的同时还具有高导热性、低泄漏率等特性,该复合材料不仅提高了地域特色的生物质材料的附加值,更为新型建筑储能材料提供了新思路.
Preparation and properties of paraffin/jujube carbon composite phase change materials
In this study,the freeze-dried powder(FDJ)of waste jujube was used as a carrier for phase change materials.The vacuum impregnation method was used to adsorb paraffin from phase change core materials,and the thermal storage capacity and thermal re-sponse efficiency of the materials were studied.Polyvinyl alcohol aqueous solution was used to reduce the leakage value of the materi-als.The results showed that the phase transition enthalpy of polyvinyl alcohol/jujube carbon paraffin carbon composite phase change material(PVA/CFDJ)was 126.41 J/g,and the thermal conductivity was 0.216 3 W/m·k,which is 60.5%higher than that of pure paraffin.In the storage-discharge heat cycle test,the enthalpy value of the PVA/CFDJ material was only reduced by about 4%after 100 cycles,and the leakage rate was reduced to 3.2%.The PVA/CFDJ composite has the characteristics of high phase transition enthalpy,high thermal conductivity and low leakage rate,which not only improve the added value of biomass materials with regional characteris-tics,but also provide new ideas for novel building energy storage materials.

freeze-dried jujube powderparaffinphase change material

时春辉、陆淑芬、胡立兵、陈浩东、吕喜风

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塔里木大学化学化工学院,新疆 阿拉尔 843300

新疆生产建设兵团第一师生态环境监测站,新疆 阿拉尔 843300

冻干枣粉 石蜡 相变材料

塔里木大学校长基金硕士项目有机无机复合材料国家重点实验室开放基金

TDZKSS202126202001011

2024

塔里木大学学报
塔里木大学

塔里木大学学报

CHSSCD
影响因子:0.313
ISSN:1009-0568
年,卷(期):2024.36(2)
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