首页|基于紧密堆积理论的深水低密度三元固相水泥浆体系

基于紧密堆积理论的深水低密度三元固相水泥浆体系

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深水浅表层固井作业过程中由于海底低温导致水泥环早期力学强度发展缓慢、内部密实度不高,易引发水气窜流,进而导致固井质量低劣甚至密封失效等复杂情况.为此,采用分形特征方程对G级油井水泥、纳米CaCO3(NC)和漂珠(CS)进行紧密堆积,然后结合室内实验评价,优选出了一套密度为 1.50 g/cm3 的具有低温早强性能的三元固相水泥浆体系,并利用抗压强度测试、XCT、SEM等方法对紧密堆积体系的增强机理进行了表征和分析.研究结果表明:①三元紧密堆积体系早期力学强度发展快速,在 10℃的低温条件下,24 h抗压强度可达 3.5 MPa以上;②相比于相同密度的NC二元体系和CS二元体系,孔隙率降低了19.10%~33.05%,抗压强度提高了 7.0%~21.1%;③NC可以为水泥水化提供成核位点、填充细化孔隙,CS可以部分替代水而提高体系致密性,在两种材料的协同作用和紧密堆积效应下可实现早期力学强度的快速发展.结论认为,三元固相级配水泥浆体系利用紧密堆积理论发挥了 3 种材料的各自优势,进而实现了早期力学强度的快速发展,对于深水井表层套管固井作业防止水气窜流具有很好的理论指导意义和应用推广价值.
Deepwater low-density ternary solid phase cement slurry system based on close packing theory
In the process of cementing in deepwater shallow formations,the low temperature at the sea floor results in slow development of the early mechanical strength of the cement sheath and low internal compactness of the cement sheath,which leads to water and gas channeling,causing poor cementing quality and even seal failure and other complex accidents.In this paper,the fractal characteristics equation is used for the close packing of G-grade oil-well cement,nano CaCO3(NC)and cenospheres(CS).Then,a set of ternary solid-phase cement slurry system with a density of 1.50 g/cm3 and the properties of low temperature and early strength is selected through indoor experimental evaluation.Finally,the strengthening mechanisms of close packing system are characterized and analyzed by means of compressive strength test,XCT and SEM.And the following research results are obtained.First,the mechanical strength of the ternary close packing system develops rapidly in the early stage,and the compressive strength at 24 h can reach more than 3.5 MPa under 10℃.Second,compared with the NC binary system and the CS binary system with the same density,the ternary system is 19.10%-33.05%lower in porosity and 7.0%-21.1%higher in compressive strength.Third,NC can provide nucleation sites for cement hydration and fill and refine the pores,and CS can partially replace the water to improve the densification of the system.Under the synergistic effect of these two materials and the close packing effect,the early mechanical strength can develop rapidly.In conclusion,the ternary solid-phase cement slurry system gives full play to the advantages of three kinds of materials on the basis of close pacing theory,so as to realize the rapid development of early mechanical strength,which has certain theoretical significance and application value for preventing water and gas channeling during the cementing operation of surface casing in deepwater wells.

DeepwaterLow temperatureLow-density cement slurryFractal theoryCompressive strength

郑少军、谷怀蒙、刘天乐、陈宇、蒋国盛、王韧、代天、秦榜伟、徐浩、万涛

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中国地质大学工程学院

岩土钻掘与防护教育部工程研究中心

中国海油研究总院有限责任公司

中国石油工程技术研究院有限公司

中国石油渤海钻探第一录井公司

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深水 低温 低密度固井水泥浆 分形理论 抗压强度

国家自然科学基金国家高层次人才特殊支持计划中央高校基本科研业务费专项资金(中国地质大学)优秀青年团队项目

42072343107-KZ23Z20016107-G1323523046

2024

天然气工业
四川石油管理局 中国石油西南油气田公司 中国石油川庆钻探工程公司

天然气工业

CSTPCD北大核心EI
影响因子:2.298
ISSN:1000-0976
年,卷(期):2024.44(2)
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