首页|鄂尔多斯盆地寒武系—奥陶系碳酸盐岩储层固体沥青特征、成因及其油气地质意义

鄂尔多斯盆地寒武系—奥陶系碳酸盐岩储层固体沥青特征、成因及其油气地质意义

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鄂尔多斯盆地寒武系—奥陶系古老碳酸盐岩储层是天然气勘探的重要接替领域,近期在该套地层中发现了固体沥青,研究固体沥青特征及成因可以更准确地认识油气成藏的过程.为此,运用岩心、显微镜、扫描电镜观察,结合激光拉曼、X射线能谱以及饱和烃色谱—质谱等分析测试手段,分析了固体沥青的形态、元素组成、成熟度以及生物标志化合物等特征,研究了固体沥青成因类型以及演化过程,并探讨了不同成因固体沥青的分布及其油气地质意义.研究结果表明:①寒武系—奥陶系碳酸盐岩储层固体沥青热演化程度普遍较高,充填在裂缝、缝合线以及晶间孔隙中,且方解石脉体中发育沥青包裹体;②沥青成因类型以热化学蚀变(TCA)成因为主,并发育硫酸盐热化学还原作用(TSR)成因以及气侵脱沥青成因沥青,TSR和TCA形成的沥青反射率高,热演化程度较高,其中TSR形成的沥青S/C较高,而气侵脱沥青形成的沥青反射率低,部分可见气孔;③TCA成因沥青在研究区寒武系—奥陶系均有分布;而TSR成因沥青和气侵脱沥青主要分布在盆地中部的马家沟组;④TSR成因沥青形成时间早于TCA成因沥青,并形成于原油充注且水溶硫酸盐供给充分的地区,随着地层温度逐渐升高,原油发生裂解形成TCA成因沥青,而气侵脱沥青形成于后期地层抬升过程中天然气侵入导致残留原油发生的脱沥青作用.结论认为,3 种不同成因的固体沥青形成机制的差异说明研究区经历了原油充注、裂解生成油型气、蚀变改造等油气成藏演化过程,研究认识对于深层—超深层油气形成演化和成藏潜力分析具有较好的科学意义和应用价值.
Characteristics,genesis,and petroleum geological implications of solid bitumen in Cambrian-Ordovician carbonate reservoirs in the Ordos Basin
The Cambrian-Ordovician ancient carbonate reservoir is an important replacement area for natural gas exploration in the Ordos Basin.Recently,solid bitumen is discovered in the Cambrian-Ordovician carbonate reservoir in the Ordos Basin.The study on the characteristics and genesis of solid bitumen is conducive to understanding the process of hydrocarbon accumulation more accurately.Therefore,by means of core,microscopic,and scanning electron microscope observation,combined with laser Raman,X-ray energy spectrum,and saturated hydrocarbon chromatogram-mass spectra analysis and test,the paper analyzes the morphology,elemental composition,maturity,and biomarker compounds of solid bitumen,investigates the genesis types and evolution processes of solid bitumen,and discusses the distribution and petroleum geological implications of solid bitumen of different genesis.The following results are obtained.First,solid bitumen of the Cambrian-Ordovician carbonate reservoirs in the Ordos Basin exhibits a high degree of thermal evolution,and it fills fractures,sutures and intergranular pores,while bitumen inclusions are developed on calcite veins.Second,thermal chemical alteration(TCA)is the dominant genesis type of bitumen,and thermochemical sulfate reduction(TSR)and gas deasphalting also contribute to its formation.The bitumen formed by TSR and TCA has a high reflectance and a high degree of thermal evolution.The TSR genetic bitumen has a higher S/C ratio,while the bitumen formed by gas invasion deasphalting has a lower reflectance,with gas holes visible locally.Third,the TCA genetic bitumen is distributed through the Cambrian-Ordovician in the study area,while the bitumen of TSR and gas invasion deasphalting origins are mainly distributed in the Majiagou Formation in the central basin.Forth,compared with TCA genetic bitumen,TSR genetic bitumen is earlier in formation time,and forms in the regions with oil charging and sufficient water-soluble sulfate.As the formation temperature rises gradually,oil cracking occurs,resulting in the formation of TCA genetic bitumen.Gas invasion deasphalting is formed by the deasphalting process of residual oil caused by the invasion of natural gas during the late uplift process.In conclusion,the differences in the formation mechanisms of the three different types of solid bitumen indicate that the study area has experienced the hydrocarbon accumulation evolution process such as oil charging,oil cracking into oil type gas,and alteration and transformation.The research results are of great scientific significance and application value for analyzing the formation,evolution and accumulation potential of deep and ultradeep oil and gas.

Ordos BasinCambrian-OrdovicianAncient carbonate rockSolid bitumenThermochemical sulfate reduction(TSR)Oil crackingGas invasion deasphalting

王怡帅、贾连奇、范立勇、马占荣、罗晓容、张洁、石可爱、秦彪

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西北大学地质学系

大陆动力学国家重点实验室·西北大学

低渗透油气田勘探开发国家工程实验室

中国石油长庆油田公司勘探开发研究院

中国石油长庆油田公司勘探事业部

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鄂尔多斯盆地 寒武系—奥陶系 古老碳酸盐岩 固体沥青 硫酸盐热化学还原作用 原油裂解 气侵脱沥青

2024

天然气工业
四川石油管理局 中国石油西南油气田公司 中国石油川庆钻探工程公司

天然气工业

CSTPCD北大核心EI
影响因子:2.298
ISSN:1000-0976
年,卷(期):2024.44(12)