首页|Vacancy healing for stable perovskite solar cells via bifunctional potassium tartrate

Vacancy healing for stable perovskite solar cells via bifunctional potassium tartrate

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Perovskite solar cell has gained widespread attention as a promising technology for renewable energy.However,their commercial viability has been hampered by their long-term stability and potential Pb leakage.Herein,we demonstrate a bifunctional passivator of the potassium tartrate(PT)to address both challenges.PT minimizes the Pb leakage in perovskites and also heals cationic vacancy defects,resulting in improved device performance and stability.Benefiting from PT modification,the power conversion efficiency(PCE)is improved to 23.26%and the Pb leakage in unencapsulated films is significantly reduced to 9.79 ppm.Furthermore,the corresponding device exhibits no significant decay in PCE after tracking at the maximum power point(MPP)for 2000 h under illumination(LED source,100 mW cm-2).

PerovskitePotassium tartrateLead leakageLong-term stability

Jing Dou、Yue Ma、Xiuxiu Niu、Wentao Zhou、Xueyuan Wei、Jie Dou、Zhenhua Cui、Qizhen Song、Tinglu Song、Huanping Zhou、Cheng Zhu、Yang Bai、Qi Chen

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Experimental Centre for Advanced Materials,School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China

Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials,Key Laboratory of Polymer Chemistry and Physics of Ministry of Education,BIC-ESAT,School of Materials Science and Engineering,Peking University,Beijing 100871,China

National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of China

52172182219750282201154037722005035U21A20172

2024

能源化学
中国科学院大连化学物理研究所 中国科学院成都有机化学研究所

能源化学

CSTPCDEI
影响因子:0.654
ISSN:2095-4956
年,卷(期):2024.88(1)
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