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MXenes:Versatile 2D materials with tailored surface chemistry and diverse applications

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MXenes,the most recent addition to the 2D material family,have attracted significant attention owing to their distinctive characteristics,including high surface area,conductivity,surface characteristics,mechanical strength,etc.This review begins by presenting MXenes,providing insights into their struc-tural characteristics,synthesis methods,and surface functional groups.The review covers a thorough analysis of MXene surface properties,including surface chemistry and termination group impacts.The properties of MXenes are influenced by their synthesis,which can be fluorine-based or fluorine-dependent.Fluorine-based synthesis techniques involve etching with fluorine-based reagents,mainly including HF or LiF/HCI,while fluorine-free methods include electrochemical etching,chemical vapor deposition(CVD),alkaline etching,Lewis acid-based etching,etc.These techniques result in the emer-gence of functional groups such as-F,-O,-OH,-Cl,etc.on the MXenes surface,depending on the syn-thesis method used.Properties of MXenes,such as electrical conductivity,electronic properties,catalytic activity,magnetic properties,mechanical strength,and chemical and thermal stability,are examined,and the role of functional groups in determining these properties is explored.The review delves into the diverse applications of MXenes,encompassing supercapacitors,battery materials,hydrogen storage,fuel cells,electromagnetic interference(EMI)shielding,pollutant removal,water purification,flexible elec-tronics,sensors,additive manufacturing,catalysis,biomedical and healthcare fields,etc.Finally,this arti-cle outlines the challenges and opportunities in the current and future development of MXenes research,addressing various aspects such as synthesis scalability,etching challenges,and multifunctionality,and exploring novel applications.The review concludes with future prospects and conclusions envisioning the impact of MXenes on future technologies and innovation.

MXenes2D materialsSurface chemistryMXenes structureSynthesisApplications

Sunil Kumar、Nitu Kumari、Yongho Seo

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Department of Nanotechnology and Advanced Materials Engineering and HMC Sejong University,Seoul 05006,South Korea

School of Studies in Chemistry,Jiwaji University,Gwalior 474011,India

National Research Foundation of Korea(NRF)Grant funded by the Korean government(MSIT)National Research Foundation of Korea(NRF)Grant funded by the Korean government(MSIT)Korea Institute for Advancement of Technology(KIAT)grant funded by the Korean Government(MOTIE)(The Competency Development P

NRF-2020R1A6A1A030434352020R1A2C1099862P0012451

2024

能源化学
中国科学院大连化学物理研究所 中国科学院成都有机化学研究所

能源化学

CSTPCDEI
影响因子:0.654
ISSN:2095-4956
年,卷(期):2024.90(3)
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