Electrocatalytic CO2 reduction to C2H4:From lab to fab

扫码查看

原文链接

NETL
NSTL
万方数据

外文摘要：The global concerns of energy crisis and climate change,primarily caused by carbon dioxide(CO2),are of utmost importance.Recently,the electrocatalytic CO2 reduction reaction(CO2RR)to high value-added multi-carbon(C2+)products driven by renewable electricity has emerged as a highly promising solution to alleviate energy shortages and achieve carbon neutrality.Among these C2+products,ethylene(C2H4)holds particular importance in the petrochemical industry.Accordingly,this review aims to establish a connection between the fundamentals of electrocatalytic CO2 reduction reaction to ethylene(CO2RR-to-C2H4)in laboratory-scale research(lab)and its potential applications in industrial-level fabrication(fab).The review begins by summarizing the fundamental aspects,including the design strategies of high-performance Cu-based electrocatalysts and advanced electrolyzer devices.Subsequently,innovative and value-added techniques are presented to address the inherent challenges encountered during the implementations of CO2RR-to-C2H4 in industrial scenarios.Additionally,case studies of the techno-economic analysis of the CO2RR-to-C2H4 process are discussed,taking into factors such as cost-effectiveness,scalability,and market potential.The review concludes by outlining the perspectives and challenges associated with scaling up the CO2RR-to-C2H4 process.The insights presented in this review are expected to make a valuable contribution in advancing the CO2RR-to-C2H4 process from lab to fab.

外文关键词：

CO2 electroreduction reactionEthyleneGas diffusion electrodeMachine learningDensity functional theoryTechno-economic analysis

作者：

Zeyu Guo、Fabao Yang、Xiaotong Li、Huiwen Zhu、Hainam Do、Kam Loon Fow、Jonathan D.Hirst、Tao Wu、Qiulin Ye、Yaqi Peng、Hao Bin Wu、Angjian Wu、Mengxia Xu

展开 >

作者单位：

Department of Chemical and Environmental Engineering,and New Materials Institute,University of Nottingham Ningbo China,Ningbo 315100,Zhejiang,China

Key Laboratory of Carbonaceous Waste Processing and Process Intensification of Zhejiang Province,University of Nottingham Ningbo China,Ningbo 315100,Zhejiang,China

Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute,University of Nottingham Ningbo China,Ningbo 315100,Zhejiang,China

State Key Laboratory of Clean Energy Utilization,Department of Energy Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China

Institute for Composites Science Innovation(InCSI)and State Key Laboratory of Silicon and Advanced Semiconductor Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China

School of Chemistry,University of Nottingham,University Park,Nottingham NG7 2RD,UK

Baima Lake Laboratory,Hangzhou 310053,Zhejiang,China

展开 >

基金：

Zhejiang Provincial Department of Science and Technology under its Provincial Key Laboratory Program中央高校基本科研业务费专项中央高校基本科研业务费专项中央高校基本科研业务费专项Pioneer Research and Development Program of Zhejiang Provincefinancial aid from National Natural Science Foundation of China浙江省自然科学基金中央高校基本科研业务费专项Royal Academy of Engineering under the Chairs in Emerging Technologies schemeUniversity of Nottingham Ningbo China for providing a full PhD scholarship

项目编号：

2020E100182022LHJH01-032022ZFJH042022QZJH142022C0304022005266LR21E0200032021FZZX001-09CiET2021_17

出版年：

2024

DOI：

10.1016/j.jechem.2023.11.019

能源化学

中国科学院大连化学物理研究所中国科学院成都有机化学研究所

能源化学

CSTPCDEI

影响因子：0.654

ISSN：2095-4956

年,卷(期)：2024.90(3)

参考文献量229