首页|Biomass valorization via electrocatalytic carbon-carbon bond cleavage
Biomass valorization via electrocatalytic carbon-carbon bond cleavage
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Renewable electrocatalytic upgrading of biomass feedstocks into valuable chemicals is one of the promis-ing strategies to relieve the pressure of traditional energy-based systems.Through electrocatalytic car-bon-carbon bond cleavage of high selectivity,various functionalized molecules,such as organic acids,amides,esters,and nitriles,have great potential to be accessed from biomass.However,it has merely received finite concerns and interests in the biorefinery.This review first showcases the research progress on the electrocatalytic conversion of lipid/sugar-and lignin-derived molecules(e.g.,glycerol,meso-erythritol,xylose,glucose,1-phenylethanol,and cyclohexanol)into organic acids via specific carbon-car-bon bond scission processes,with focus on disclosing reaction mechanisms,recognizing actual active species,and collecting feasible modification strategies.For the guidance of further extensive studies on biomass valorization,organic transformations via a variety of reactions,including decarboxylation,ring-opening,rearrangement,reductive hydrogenation,and carboxylation,are also disclosed for the con-struction of similar carbon skeletons/scaffolds.The remaining challenges,prospective applications,and future objectives in terms of biomass conversion are also proposed.This review is expected to provide references to develop renewed electrocatalytic carbon-carbon bond cleavage transformation paths/strategies for biomass upgrading.
ElectrocatalysisBiomass conversionCarbon-carbon bond cleavageOrganic acids
National Key Laboratory of Green Pesticide,Key Laboratory of Green Pesticide & Agricultural Bioengineering,Ministry of Education,State-Local Joint Laboratory for Comprehensive Utilization of Biomass,Center for R&D of Fine Chemicals,Guizhou University,Guiyang 550025,Guizhou,China
Departamento de Quimica Organica.Universidad de Cordoba,Campus de Rabanales,Edifficio Marie Curie(C-3),Ctra Nnal Ⅳ,Km.396,E-14014 Cordoba,Spain
Laboratory of Bioproduct Chemistry,Centre of Innovative and Applied Bioprocessing(CIAB),Mohali 140306,Punjab,India
国家自然科学基金Guizhou Provincial Science and Technology ProjectGuizhou Provincial Science and Technology ProjectGuizhou Provincial Higher Education Institution ProgramRUDN University Strategic Academic Leadership Program
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